One-Pot Synthesis of Zincblende CuInSe2 Nanocrystals via a Green Solution Reaction Route

被引：2
作者：
Li, Dehui [1 ]
Qi, Weichen [1 ]
Xiao, Jinglei [1 ]
Yang, Jing [1 ]
Wu, Yong [1 ]
Gao, Qiao [1 ]
Zhai, Shengyong [2 ]
机构：
[1] Changchun Univ Chinese Med, Sch Pharmaceut Sci, 1035 Boshuo Rd, Changchun 130117, Jilin, Peoples R China
[2] Changchun Univ Chinese Med, Chinese Med & Biol Engn Res & Dev Ctr, Changchun 130117, Jilin, Peoples R China
来源：
NANO | 2017年 / 12卷 / 09期
基金：
中国国家自然科学基金;
关键词：
CuInSe2; nanocrystal; one-pot synthesis; green chemistry; zincblende structure; multitenary metal selenicles; PHOSPHINE-FREE SYNTHESIS; SOLAR-CELLS; SELENIDE NANOCRYSTALS; QUANTUM CONFINEMENT; LOW-COST; NANOPARTICLES; CHALCOPYRITE; PRECURSOR; TEMPERATURE; DISSOLUTION;
D O I：
10.1142/S1793292017501077
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The facile and ecofriendly method for the synthesis of a suitable colloidal nanocrystal ink plays an important role in the field of solar cells. Here, we describe our recent efforts toward this direction by a simple one-pot colloidal method to engineer CuInSe2 (CISe) nanocrystals with cubic zinc-blende (ZB) structure. The suitable band gap value and obvious photoresponse of the as-synthesized CISe nanocrystals indicate their potential application in the field of thin film solar cells. In addition, a possible crystal growth mechanism has been suggested for the formation of ZB CISe.
引用
收藏
页数：8
相关论文
共 34 条
[1]   Towards low-cost, environmentally friendly printed chalcopyrite and kesterite solar cells [J].
Azimi, Hamed ;
Hou, Yi ;
Brabec, Christoph J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (06) :1829-1849
[2]   Synthesis and characterization of colloidal CuInS2 nanoparticles from a molecular single-source precursor [J].
Castro, SL ;
Bailey, SG ;
Raffaelle, RP ;
Banger, KK ;
Hepp, AF .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (33) :12429-12435
[3]   Nanocrystalline chalcopyrite materials (CuInS2 and CuInSe2) via low-temperature pyrolysis of molecular single-source precursors [J].
Castro, SL ;
Bailey, SG ;
Raffaelle, RP ;
Banger, KK ;
Hepp, AF .
CHEMISTRY OF MATERIALS, 2003, 15 (16) :3142-3147
[4]   The growth of Cu2-xSe thin films using nanoparticles [J].
Cho, Ara ;
Ahn, Sejin ;
Yun, Jae Ho ;
Gwak, Jihye ;
Ahn, Seung Kyu ;
Shin, Keeshik ;
Yoo, Jinsu ;
Song, Hyunjoon ;
Yoon, Kyunghoon .
THIN SOLID FILMS, 2013, 546 :299-307
[5]   Phosphine-Free Synthesis of p-Type Copper(I) Selenide Nanocrystals in Hot Coordinating Solvents [J].
Deka, Sasanka ;
Genovese, Alessandro ;
Zhang, Yang ;
Miszta, Karol ;
Bertoni, Giovanni ;
Krahne, Roman ;
Giannini, Cinzia ;
Manna, Liberato .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :8912-+
[6]   AgInSe2 nanorods:: A semiconducting material for saturable absorber [J].
Elim, Hendry I. ;
Ji, Wei ;
Ng, Meng-Tack ;
Vittal, Jagadese J. .
APPLIED PHYSICS LETTERS, 2007, 90 (03)
[7]   Development of CuInSe2 nanocrystal and nanoring inks for low-cost solar cells [J].
Guo, Qiiie ;
Kim, Suk Jun ;
Kar, Mahaprasad ;
Shafarman, William N. ;
Birkmire, Robert W. ;
Stach, Eric A. ;
Agrawal, Rakesh ;
Hillhouse, Hugh W. .
NANO LETTERS, 2008, 8 (09) :2982-2987
[8]   Solvothermal Synthesis of Zincblende and Wurtzite CuInS2 Nanocrystals and Their Photovoltaic Application [J].
Huang, Wan-Chen ;
Tseng, Chih-Hsiao ;
Chang, Shu-Hao ;
Tuan, Hsing-Yu ;
Chiang, Chien-Chih ;
Lyu, Lian-Ming ;
Huang, Michael H. .
LANGMUIR, 2012, 28 (22) :8496-8501
[9]   Investigating the Control by Quantum Confinement and Surface Ligand Coating of Photocatalytic Efficiency in Chalcopyrite Copper Indium Diselenide Nanocrystals [J].
Jana, Atanu ;
Lawrence, Katie N. ;
Teunis, Meghan B. ;
Mandal, Manik ;
Kumbhar, Amar ;
Sardar, Rajesh .
CHEMISTRY OF MATERIALS, 2016, 28 (04) :1107-1120
[10]   Phosphine-free synthesis of CdSe nanocrystals [J].
Jasieniak, J ;
Bullen, C ;
van Embden, J ;
Mulvaney, P .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (44) :20665-20668
1234