Research Progress on Cross-coupling Reactions of Alkenylaluminum with Electrophilic Reagents

被引：13

作者：

Li, Qing Han ^{[1
]}

Shao, Xue Bei ^{[1
]}

Ding, Yong ^{[1
]}

Wen, Chang ^{[1
]}

Zhao, Zhi Gang ^{[1
]}

机构：

[1] Southwest Univ Nationalities, Coll Chem & Environm Protect Engn, POB 610041, Chengdu, Sichuan, Peoples R China

来源：

CURRENT ORGANIC CHEMISTRY | 2018年 / 22卷 / 15期

关键词：

Alkenylaluminum reagents; Cross-coupling reaction; C-C bond formation; C-N bond formation; research progress; nucleophiles; HIGHLY EFFICIENT SYNTHESIS; NICKEL-CATALYZED REACTION; ALKYNYL BROMIDES; BOND; HYDROALUMINATION; ALKENYLALANES; ACTIVATION; PYRIDINE; ACIDS;

D O I：

10.2174/1385272822666180704143509

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkenylaluminum reagents are good nucleophiles for organic reactions because of their high reactivities, the high Lewis acidity of the aluminum center, and their low toxicities. Therefore, alkenylaluminum reagents are widely applied in many of organic reactions. This review summarizes the recent advance of the alkenylaluminum reagents applied in cross-coupling reactions, involving various reaction systems, properties of reaction and synthetic application.

引用

页码：1523 / 1535

页数：13

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