Synthesis and Properties of Polyaniline/ferrites Nanocomposites

被引:0
作者
Elsayed, A. H. [1 ]
Eldin, M. S. Mohy [2 ]
Elsyed, A. M. [2 ]
Elazm, A. H. Abo
Younes, E. M. [1 ]
Motaweh, H. A. [1 ]
机构
[1] Univ Alexandria, Dept Phys, Fac Sci, Damanhour Branch, Alexandria, Egypt
[2] Adv Technol & New Mat Res Inst, New Boarg El Arab City 21934, Alexandria, Egypt
关键词
Polyaniline; nanocomposites; magnetic properties; ferrite; conducting polymers; thermal stability; MAGNETIC-PROPERTIES; PARTICLE-SIZE; COMPOSITES; FERRITE; NANOPARTICLES; TEMPERATURE; COFE2O4; FE3O4; FE3O4-POLYANILINE; CARBON;
D O I
暂无
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Polyaniline (PANI-EB) containing MFe2O4 (M is an element in a divalent state; M2+ = Fe2+, Co2+, Ni2+, Mn2+, and Zn2+) were prepared by chemical method. The results of this investigation indicate that; i) the size of MFe2O4 in PANI is in the range 10 to 20 nm. ii) the MFe2O4 nanoparticles have the characteristic reflections of the Fd-3m spinel cubic structure. iii) the presence of ferromagnetic phase in PANI/Fe3O4 and PANI/CoFe2O4 samples, while samples containing Ni2+, Mn2+, and Zn2+ showed a superparamagnetic behavior. The results of Thermogravimetric analysis indicated that the addition of MFe2O4 nanoparticles to PANI improved the nanocomposites thermal stability. The interaction between MFe2O4 nanoparticles and PANI matrix may be occurred by the formation of the hydrogen bonding between the amine group of PANI and Oxygen of MFe2O4.
引用
收藏
页码:206 / 221
页数:16
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