A hydroxytetradecatrienoic acid from Mycosphaerella rubella

被引：14

作者：

Arnone, A ^{[1
]}

Nasini, G ^{[1
]}

de Pava, OV ^{[1
]}

机构：

[1] Politecn Milan, Dipartimento Chim, CNR, Ctr Studio Sostanze Organ Nat, I-20121 Milan, Italy

来源：

PHYTOCHEMISTRY | 1998年 / 48卷 / 03期

关键词：

Mycosphaerella rubella; Ascomycetes; dihydroxytetradecatrienoic acids; structural elucidation; absolute configuration;

D O I：

10.1016/S0031-9422(98)00027-2

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Investigations on the acidic fractions from extracts of a culture of Mycosphaerella rubella led to the isolation of a new unsaturated dihydroxy acid, 6,13-dihydraxytetradeca-2,4,8-trienoic acid, and two of its derivatives, which are probably artifacts. Their structures were determined on the basis of H-1 and C-13 NMR evidence. The absolute configuration of the chiral centres of the new acid was elucidated using the modified Mosher's method. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：507 / 510

页数：4

共 7 条

[1] SECONDARY MOLD METABOLITES .15. STRUCTURE ELUCIDATION OF RUBELLIN-A AND RUBELLIN-B, 2 NOVEL ANTHRAQUINONE METABOLITES FROM MYCOSPHAERELLA-RUBELLA [J].

ARNONE, A ;

CAMARDA, L ;

NASINI, G ;

ASSANTE, G .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (02) :255-260

[2]

ARNONE A, 1989, GAZZ CHIM ITAL, V119, P35

[3] SECONDARY MOLD METABOLITES .32. A REINVESTIGATION OF THE STRUCTURE OF BIRULOQUINONE, A 9,10-PHENANTHRENEQUINONE ISOLATED FROM MYCOSPHAERELLA-RUBELLA [J].

ARNONE, A ;

NASINI, G ;

DEPAVA, OV .

PHYTOCHEMISTRY, 1991, 30 (08) :2729-2731

[4] A NEW HYDROXYTETRADECATRIENOIC ACID AND ITS GLYCERYL ESTERS FROM VALSA-AMBIENS [J].

JIAO, Y ;

YOSHIHARA, T ;

AKIMOTO, M ;

ICHIHARA, A .

PHYTOCHEMISTRY, 1995, 38 (02) :419-422

[5] ABSOLUTE-CONFIGURATIONS OF MARINE DITERPENES POSSESSING A XENICANE SKELETON - AN APPLICATION OF AN ADVANCED MOSHER METHOD [J].

OHTANI, I ;

KUSUMI, T ;

ISHITSUKA, MO ;

KAKISAWA, H .

TETRAHEDRON LETTERS, 1989, 30 (24) :3147-3150

[6] HYDROXYLATED UNSATURATED FATTY-ACID FROM CULTURES OF A FILOBOLETUS SPECIES [J].

SIMON, B ;

ANKE, T ;

STERNER, O .

PHYTOCHEMISTRY, 1994, 36 (03) :815-816

[7]

Turner WB., 1983, FUNGAL METABOLITES

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