Synthesis of esters via sp3 C-H functionalisation

被引：72
作者：
Majji, Ganesh [1 ]
Rout, Saroj K. [1 ]
Rajamanickam, Suresh [1 ]
Guin, Srimanta [1 ]
Patel, Bhisma K. [1 ]
机构：
[1] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, India
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 35期
关键词：
CROSS-COUPLING REACTION; INTERMOLECULAR RADICAL REACTION; FREE OXIDATIVE ESTERIFICATION; CATALYZED ALLYLIC OXIDATION; ALPHA-ACETOXY KETONES; CARBOXYLIC-ACIDS; EFFICIENT SYNTHESIS; PRINS CYCLIZATIONS; CARBONYL-COMPOUNDS; TERMINAL ALKENES;
D O I：
10.1039/c6ob01250g
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Oxidative C-O bond formation via sp(3) C-H functionalisation represents an attractive approach for the synthesis of esters. This review focuses on the recent advances of sp(3) C-H bond functionalisation strategies for ester synthesis from unconventional precursors using transition metal/metal free catalysts in combination with various oxidants. Various classes of esters and the mechanisms of their formation are discussed with numerous examples.
引用
收藏
页码：8178 / 8211
页数：34
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