Electron paramagnetic resonance study of X-irradiated tri-coordinated copper(I) complexes

被引：2
|
作者：
Ramaprabhu, S [1 ]
机构：
[1] Indian Inst Technol, Dept Phys, Magnetisme & Mat Magnet Lab, Madras 600036, Tamil Nadu, India
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1999年 / 478卷 / 1-3期
关键词：
electron paramagnetic resonance; radiation effects; organic crystals; single crystal; copper(I) complexes;
D O I：
10.1016/S0022-2860(98)00619-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
X-irradiation of single crystals of several tri-coordinated Cu(I) monomer and dimer complexes studied by EPR revealed that Cu(I) monomer complexes form Cu(II) complexes while X-irradiation of the Cu(I) dimer complexes has no such effect. The formation of Cu(II) complexes is attributed to the addition of a radiogenic atom on the Cu(I) precursor. The absence of any structural changes due to the X-irradiation of the Cu(I) dimer complexes is discussed based on the electronic structure of these complexes. (C) 1999 Elsevier Science B.V. All rights reserved.
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页码：29 / 35
页数：7
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