p-Carboxyl-N-salicylideneanilines: Simple but efficient chromophores for one-dimensional microrods with aggregation-induced emission enhancement (AIEE) characteristics

被引:23
作者
Chen, Xiao-tong [1 ]
Xiang, Yu [2 ]
Song, Pan-Shu [1 ]
Wei, Rui-rui [1 ]
Zhou, Zhao-juan [1 ]
Li, Kai [1 ]
Tong, Ai-jun [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China
[2] Univ Illinois, Beckman Inst, Urbana, IL 61801 USA
基金
中国国家自然科学基金;
关键词
Salicylideneanilines; Microrods; Aggregation-induced emission; enhancement; LIGHT-EMITTING-DIODES; OPTICAL WAVE-GUIDE; SOLID-STATE; MOLECULAR PACKING; FLUORESCENCE; FLUOROPHORES; PHOTOLUMINESCENCE; THERMOCHROMISM; NANOPARTICLES; FABRICATION;
D O I
10.1016/j.jlumin.2011.03.041
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
In this study, p-carboxyl-N-salicylideneaniline (pCSA) derivatives were simply synthesized by condensing salicylaldehyde and primary amine. With two planar pi-conjugated moieties linked by rotatable C-N single bond in the molecular structure, pCSA derivatives were characteristic of aggregation-induced emission enhancement (AIEE) properties, exhibiting strong fluorescence in solid state. Facilely recrystallized from organic solvent, one-dimensional (1D) microrods of pCSA were prepared with green, yellow and orange AIEE colors depending on substituents on salicylaldimine moiety. The obtained 1D microrods could be utilized as potential optical waveguides for propagating and manipulating light in miniaturized devices. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:1453 / 1459
页数:7
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