An Update on Recent Stoichiometric and Catalytic C-F Bond Cleavage Reactions by Lanthanide and Group 4 Transition-Metal Complexes

被引：94

作者：

Klahn, Marcus ^{[1
]}

Rosenthal, Uwe ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

ORGANOMETALLICS | 2012年 / 31卷 / 04期

关键词：

ZIRCONOCENE FLUORO COMPLEXES; BIS(TRIMETHYLSILYL)ACETYLENE COMPLEXES; ACTIVATION REACTIONS; HYDRODEFLUORINATION; ZIRCONIUM; CHEMISTRY; MECHANISM; CP-ASTERISK-2ZRH2; ORGANOLANTHANOIDS; FLUOROPYRIDINES;

D O I：

10.1021/om200978a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In organometallic chemistry numerous complexes are known to cleave activated and nonactivated C-F bonds of organic compounds. These reactions are either stoichiometric or catalytic and offer different possibilities for a wide range of synthetic and catalytic applications. This review attempts to summarize a selection of most important developments made since 1997 for C-F bond cleavages by lanthanide and group 4 transition-metal complexes.

引用

页码：1235 / 1244

页数：10

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