Moment fluctuations in 7 nm γ-Fe2O3 nanoparticles probed at the atomic level using Mossbauer spectroscopy

被引:15
作者
Desautels, R. D. [1 ]
Skoropata, E. [1 ]
van Lieropa, J. [1 ]
机构
[1] Univ Manitoba, Dept Phys & Astron, Winnipeg, MB R3T 2N2, Canada
关键词
D O I
10.1063/1.2830963
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have examined the local magnetism of 7 nm gamma-Fe2O3 nanoparticles as a function of temperature using transmission Mossbauer spectroscopy. Spectra indicate that the nanoparticles exhibit two different spin populations: one is due to the core Fe moments, while the other is from the surface moments. We find that the uniaxial anisotropy of the core increases with temperature from 5 to 75 K, whereupon it remains constant. Simultaneously, the surface moment fluctuations increase in frequency with warming.
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页数:3
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