Fabrication of Sr- and Co-doped lanthanum chromite interconnectors for SOFC

被引：11
作者：
Setz, L. F. G. [2 ]
Santacruz, I. [3 ]
Colomer, M. T. [1 ]
Mello-Castanho, S. R. H.
Moreno, R. [1 ]
机构：
[1] ICV CSIC, Inst Ceram & Vidrio, Madrid 28049, Spain
[2] Univ Fed Sao Carlos DEMa UFSCar, Dept Mat Engn, Sao Carlos, SP, Brazil
[3] Univ Malaga, Dept Quim Inorgan Cristalog & Mineral, E-29071 Malaga, Spain
来源：
MATERIALS RESEARCH BULLETIN | 2011年 / 46卷 / 07期
基金：
巴西圣保罗研究基金会;
关键词：
Ceramics; Oxides; X-ray diffraction; Microstructure; OXIDE FUEL-CELL; COMBUSTION SYNTHESIS; STRONTIUM; COBALT; SUSPENSIONS; TECHNOLOGY; STABILITY; POWDERS;
D O I：
10.1016/j.materresbull.2011.03.019
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Many studies have been performed dealing with the processing conditions of electrodes and electrolytes in solid oxide fuel cells (SOFCs). However, the processing of the interconnector material has received less attention. Lanthanum chromite (LaCrO(3)) is probably the most studied material as SOFCs interconnector. This paper deals with the rheology and casting behaviour of lanthanum chromite based materials to produce interconnectors for SOFCs. A powder with the composition La(0.80)Sr(0.20)Cr(0.92)CO(0).(08)O(3) was obtained by combustion synthesis. Aqueous suspensions were prepared to solids loading ranging from 8 to 17.5 vol.%, using ammonium polyacrylate (PAA) as dispersant and tetramethylammonium hydroxide (TMAH) to assure a basic pH and providing stabilization. The influence of the additives concentrations and suspension ball milling time were studied. Suspensions prepared with 24 h ball milling, with 3 wt.% and 1 wt.% of PAA and TMAH, respectively, yielded the best conditions for successful slip casting. Sintering of the green discs was performed in air at 1600 degrees C for 4 h leading to relatively dense materials. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：983 / 986
页数：4
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