Flexible electromagnetic wave absorbing composite based on 3D rGO-CNT-Fe3O4 ternary films

被引:242
作者
Li, Jinsong [1 ,2 ]
Xie, Yunzhu [1 ]
Lu, Weibang [3 ]
Chou, Tsu-Wei [2 ]
机构
[1] Beihang Univ, Sch Phys & Nucl Energy Engn, Beijing 100191, Peoples R China
[2] Univ Delaware, Dept Mech Engn, Newark, DE 19716 USA
[3] Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Suzhou 215123, Peoples R China
关键词
MICROWAVE-ABSORPTION PROPERTIES; WALLED CARBON NANOTUBES; GRAPHENE OXIDE; MAGNETIC GRAPHENE; NANOCOMPOSITES; REDUCTION; MICROSTRUCTURE; DEPOSITION;
D O I
10.1016/j.carbon.2017.11.094
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Geometry-controllable three-dimensional reduced graphene oxide (rGO) network layers on carbon nanotube (CNT)-Fe3O4 films are assembled by electrophoresis. The fabricated microstructure consists of an interconnected network of graphene and carbon nanotubes with magnetic Fe3O4 particles as the fast transport channel of charge carriers for high electrical conductivity. Building upon this unique network structure, we demonstrate the superb potential for its application as electromagnetic wave absorbing material. The minimum reflection loss of the CNT film-Fe3O4-rGO-polydimethylsiloxane (PDMS) composite with 4 layers is -50.5 dB and absorption bandwidth at -10 dB is 5.7 GHz, respectively, the thickness of this material is only 1.42 mm. Long-term cycling tests in bending and twisting deformations show >93% retention of EM wave absorption after 2000 cycles. These results suggest that such CNT film-Fe3O4-rGO composite is very promising for next generation portable electronics and wearable devices. (c) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:76 / 84
页数:9
相关论文
共 38 条
[1]   A perspective: carbon nanotube macro-films for energy storage [J].
Cao, Zeyuan ;
Wei, Bingqing .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (11) :3183-3201
[2]   Highly conductive and flexible polymer composites with improved mechanical and electromagnetic interference shielding performances [J].
Chen, Mengting ;
Zhang, Ling ;
Duan, Shasha ;
Jing, Shilong ;
Jiang, Hao ;
Luo, Meifang ;
Li, Chunzhong .
NANOSCALE, 2014, 6 (07) :3796-3803
[3]   Lightweight and Flexible Graphene Foam Composites for High-Performance Electromagnetic Interference Shielding [J].
Chen, Zongping ;
Xu, Chuan ;
Ma, Chaoqun ;
Ren, Wencai ;
Cheng, Hui-Ming .
ADVANCED MATERIALS, 2013, 25 (09) :1296-1300
[4]  
Chen ZP, 2011, NAT MATER, V10, P424, DOI [10.1038/nmat3001, 10.1038/NMAT3001]
[5]   One-pot reduction of graphene oxide at subzero temperatures [J].
Cui, Peng ;
Lee, Junghyun ;
Hwang, Eunhee ;
Lee, Hyoyoung .
CHEMICAL COMMUNICATIONS, 2011, 47 (45) :12370-12372
[6]   Electromagnetic wave absorption in reduced graphene oxide functionalized with Fe3O4/Fe nanorings [J].
Ding, Yi ;
Zhang, Long ;
Liao, Qingliang ;
Zhang, Guangjie ;
Liu, Shuo ;
Zhang, Yue .
NANO RESEARCH, 2016, 9 (07) :2018-2025
[7]   Analysis of Electrochemical Reduction Process of Graphene Oxide and its Electrochemical Behavior [J].
Gao, Mingming ;
Xu, Yanyan ;
Wang, Xinhua ;
Sang, Yuanhua ;
Wang, Shuguang .
ELECTROANALYSIS, 2016, 28 (06) :1377-1382
[8]   3D graphene-Fe3O4 nanocomposites with high-performance microwave absorption [J].
Hu, Chuangang ;
Mou, Zhongyu ;
Lu, Gewu ;
Chen, Nan ;
Dong, Zelin ;
Hu, Minjia ;
Qu, Liangti .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (31) :13038-13043
[9]   A strong and tough polymer-carbon nanotube film for flexible and efficient electromagnetic interference shielding [J].
Jia, Li-Chuan ;
Li, Meng-Zhu ;
Yan, Ding-Xiang ;
Cui, Cheng-Hua ;
Wu, Hong-Yuan ;
Li, Zhong-Ming .
JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (35) :8944-8951
[10]   High Strain Tolerant EMI Shielding Using Carbon Nanotube Network Stabilized Rubber Composite [J].
Jia, Li-Chuan ;
Yan, Ding-Xiang ;
Yang, Yingchao ;
Zhou, Dong ;
Cui, Cheng-Hua ;
Bianco, Elisabeth ;
Lou, Jun ;
Vajtai, Robert ;
Li, Bo ;
Ajayan, Pulickel M. ;
Li, Zhong-Ming .
ADVANCED MATERIALS TECHNOLOGIES, 2017, 2 (07)