Modifications of Separators for Li-S Batteries with Improved Electrochemical Performance

被引:13
作者
Yang, Dezhi [1 ,2 ]
Xiong, Xiaosong [1 ,2 ]
Zhu, Yusong [1 ,2 ]
Chen, Yuhui [1 ,2 ]
Fu, Lijun [1 ,2 ]
Zhang, Yi [1 ,2 ]
Wu, Yuping [1 ,2 ]
机构
[1] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Inst Adv Mat IAM, Nanjing 211816, Peoples R China
[2] Nanjing Tech Univ, Sch Energy Sci & Engn, Nanjing 211816, Peoples R China
基金
中国国家自然科学基金;
关键词
lithium-sulfur battery; separator; modification; gel polymer electrolyte; shuttle effect; lithium dendrites; GEL POLYMER ELECTROLYTE; LITHIUM-SULFUR BATTERIES; CARBON NANOFIBER; POLYSULFIDE SHUTTLE; COMPOSITE CATHODES; SELF-DISCHARGE; IN-SITU; NANOTUBES; CHALLENGES; CAPACITY;
D O I
10.1134/S1023193520050110
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Lithium-sulfur (Li-S) batteries are widely regarded as one of the promising next-generation secondary energy storage systems. However, some tricky challenges, such as electrically insulating elemental sulfur, shuttle effect and lithium dendrites, have been limiting its practical application. Modification of separators, which is found as a facile and low-cost settlement, has shown great advantages in solving the above three crucial problems, leading to greatly improved performance of Li-S batteries. In this paper, we summarize recent progresses on separators for Li-S batteries including coatings such as carbon materials, polymers, and inorganic materials, and tailoring multi-functional gel separators to achieve Li-S batteries with high performance. The importance and development directions of functional separators in the further commercialization of Li-S batteries are also discussed.
引用
收藏
页码:365 / 377
页数:13
相关论文
共 87 条
[11]   Taming the polysulphide shuttle in Li-S batteries by plasma-induced asymmetric functionalisation of the separator [J].
Conder, Joanna ;
Urbonaite, Sigita ;
Streich, Daniel ;
Novak, Petr ;
Gubler, Lorenz .
RSC ADVANCES, 2015, 5 (97) :79654-79660
[12]   A review on separators for lithium-sulfur battery: Progress and prospects [J].
Deng, Nanping ;
Kang, Weimin ;
Liu, Yanbo ;
Ju, Jingge ;
Wu, Dayong ;
Li, Lei ;
Hassan, Bukhari Samman ;
Cheng, Bowen .
JOURNAL OF POWER SOURCES, 2016, 331 :132-155
[13]   Stable cycling of lithium-sulfur battery enabled by a reliable gel polymer electrolyte rich in ester groups [J].
Du, Huiping ;
Li, Shizhen ;
Qu, Hongtao ;
Lu, Boyang ;
Wang, Xiaogang ;
Chai, Jingchao ;
Zhang, Huanrui ;
Ma, Jun ;
Zhang, Zhonghua ;
Cui, Guanglei .
JOURNAL OF MEMBRANE SCIENCE, 2018, 550 :399-406
[14]   Electrical Energy Storage for the Grid: A Battery of Choices [J].
Dunn, Bruce ;
Kamath, Haresh ;
Tarascon, Jean-Marie .
SCIENCE, 2011, 334 (6058) :928-935
[15]  
Evers S., 2012, ACCOUNTS CHEM RES, V46, P1125
[16]   More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects [J].
Fang, Ruopian ;
Zhao, Shiyong ;
Sun, Zhenhua ;
Wang, Wei ;
Cheng, Hui-Ming ;
Li, Feng .
ADVANCED MATERIALS, 2017, 29 (48)
[17]   Recent developments in cathode materials for lithium ion batteries [J].
Fergus, Jeffrey W. .
JOURNAL OF POWER SOURCES, 2010, 195 (04) :939-954
[18]   Core-shell structured sulfur-polypyrrole composite cathodes for lithium-sulfur batteries [J].
Fu, Yongzhu ;
Manthiram, Arumugam .
RSC ADVANCES, 2012, 2 (14) :5927-5929
[19]   Poly(vinylidene fluoride)-based hybrid gel polymer electrolytes for additive-free lithium sulfur batteries [J].
Gao, Shu ;
Wang, Kangli ;
Wang, Ruxing ;
Jiang, Mao ;
Han, Jing ;
Gu, Tiantian ;
Cheng, Shijie ;
Jiang, Kai .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (34) :17889-17895
[20]   MoS2/Celgard Separator as Efficient Polysulfide Barrier for Long-Life Lithium-Sulfur Batteries [J].
Ghazi, Zahid Ali ;
He, Xiao ;
Khattak, Abdul Muqsit ;
Khan, Niaz Ali ;
Liang, Bin ;
Iqbal, Azhar ;
Wang, Jinxin ;
Sin, Haksong ;
Li, Lianshan ;
Tang, Zhiyong .
ADVANCED MATERIALS, 2017, 29 (21)