Oligosilylanions and their reactions with zirconocene and hafnocene dichlorides

被引：0

作者：

Kayser, C ^{[1
]}

Marschner, C ^{[1
]}

机构：

[1] Graz Tech Univ, Inst Anorgan Chem, A-8010 Graz, Austria

来源：

MONATSHEFTE FUR CHEMIE | 1999年 / 130卷 / 01期

关键词：

oligosilylanions; transition metal silicon complexes;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New group 4 metallocene oligosilyl compounds (RSi(SiMe3)(2)MCp2Cl; M= Zr, R = H, Me, SiMe3, SiMe2Bu, SiMe2CMe2CHMe2, SiMe2Si(SiMe3)(3); M= Hf, R = H, SiMe3) have been synthesized by reaction of the respective oligosilyl potassium compounds with zirconocene or hafnocene dichloride.

引用

页码：203 / 206

页数：4

共 8 条

[1] REACTIONS OF CARBON-MONOXIDE WITH TRIMETHYLSILYL AND TRIS(TRIMETHYLSILYL)SILYL DERIVATIVES OF GROUP-4 METALS - SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF SILAACYL COMPLEXES [J].

CAMPION, BK ;

FALK, J ;

TILLEY, TD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (07) :2049-2056

[2] Synthesis and reactivity of 16-electron hafnocene silyl hydride complexes [J].

Casty, GL ;

Lugmair, CG ;

Radu, NS ;

Tilley, TD ;

Walzer, JF ;

Zargarian, D .

ORGANOMETALLICS, 1997, 16 (01) :8-12

[3] REACTIONS OF (ETA-5-C5H5)(ETA-5-C5ME5)ZR[SI(SIME3)3]X (X = CL, ME) COMPLEXES WITH CARBON-MONOXIDE AND THE ISOCYANIDE 2,6-ME2C6H3NC - CRYSTAL-STRUCTURE OF (ETA-5-C5H5)-(ETA-5-C5ME5)ZR[ETA-2-C(N-2,6-ME2C6H3)SI(SIME3)3]CL [J].

ELSNER, FH ;

TILLEY, TD ;

RHEINGOLD, AL ;

GEIB, SJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 358 (1-3) :169-183

[4]

GILMAN H, 1965, CHEM IND-LONDON, P848

[5]

Marschner C, 1998, EUR J INORG CHEM, P221

[6]

MORRIS GA, 1980, J AM CHEM SOC, V102, P428, DOI 10.1021/ja00521a097

[7]

Tilley T.D., 1989, The Chemistry of Organic Silicon Compounds, P1415

[8]

TILLEY TD, 1991, SILICON HETEROATOM B, P309

← 1 →