A zwitterionic gold(I) complex from an ambiphilic diphosphino-alane ligand

被引：71

作者：

Sircoglou, Marie ^{[2
]}

Bouhadir, Ghenwa ^{[2
]}

Saffon, Nathalie ^{[3
]}

Miqueu, Karinne ^{[1
]}

Bourissou, Didier ^{[2
]}

机构：

[1] CNRS, Inst Pluridisciplinaire Rech Environm & Mat, UMR 5254, Equipe Chim Phys, Ave Univ,BP 1155, F-64013 Pau, France

[2] CNRS, Equipe Ligands Bifonctionnels, Lab Heterochim Fondamentale & Appl, UMR 5069, F-31062 Toulouse 9, France

[3] Struct Federat Toulousaine Chim Mol, FR 2599, F-31062 Toulouse 9, France

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 08期

关键词：

D O I：

10.1021/om800101s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diphosphino-alane ligand ClAl[C6H4(o-P-i-Pr-2)](2) (1) has been prepared and reacted with [AuCl(SMe2)]. X-ray analyses and DFT calculations substantiate the preference of the ensuing complex 2 for a zwitterionic structure, resulting from internal chloride abstraction by aluminum over a neutral form featuring an Au -> Al interaction.

引用

页码：1675 / 1678

页数：4

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