Ethanol and water adsorption in methanol-derived ZIF-71

被引:99
作者
Lively, Ryan P. [1 ]
Dose, Michelle E. [2 ]
Thompson, Joshua A. [2 ]
McCool, Benjamin A. [1 ]
Chance, Ronald R. [1 ,2 ]
Koros, William J. [2 ]
机构
[1] Algenol Biofuels, Bonita Springs, FL 34315 USA
[2] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA
关键词
ALCOHOLS;
D O I
10.1039/c1cc12728d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions.
引用
收藏
页码:8667 / 8669
页数:3
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