Design and synthesis of cyclodextrin-based rotaxanes and polyrotaxanes

被引:26
作者
Nakashima, N [1 ]
Kawabuchi, A [1 ]
Murakami, H [1 ]
机构
[1] Nagasaki Univ, Fac Engn, Dept Appl Chem, Nagasaki 852, Japan
关键词
rotaxane; polyrotaxane; cyclodextrin; molecular recognition; light-driven molecular shuttle; lipid; lipid bilayer; supramolecule; nanotube;
D O I
10.1023/A:1008084015958
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rotaxanes are compounds in which a ring is threaded by a chain having bulky terminal cap groups. In this article, we review the design, synthesis and characterization of rotaxanes and polyrotaxanes of cyclodextrins threaded by an alkyl chain or a poly(ethylene glycol) as well as the synthesis of a light-driven molecular shuttle based on a cyclodextrin-rotaxane.
引用
收藏
页码:363 / 373
页数:11
相关论文
共 27 条
  • [1] Interlocked and intertwined structures and superstructures
    Amabilino, DB
    Stoddart, JF
    [J]. CHEMICAL REVIEWS, 1995, 95 (08) : 2725 - 2828
  • [2] A MOLECULAR SHUTTLE
    ANELLI, PL
    SPENCER, N
    STODDART, JF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (13) : 5131 - 5133
  • [3] A PHOTOCHEMICALLY DRIVEN MOLECULAR MACHINE
    BALLARDINI, R
    BALZANI, V
    GANDOLFI, MT
    PRODI, L
    VENTURI, M
    PHILP, D
    RICKETTS, HG
    STODDART, JF
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1993, 32 (09) : 1301 - 1303
  • [4] Bender M.L., 1978, Cyclodextrin Chemistry
  • [5] BORN M, 1991, MAKROMOL CHEM-RAPID, V12, P471
  • [6] Preparation and characterization of inclusion complexes of polyisobutylene with cyclodextrins
    Harada, A
    Suzuki, S
    Okada, M
    Kamachi, M
    [J]. MACROMOLECULES, 1996, 29 (17) : 5611 - 5614
  • [7] COMPLEX-FORMATION BETWEEN POLY(ETHYLENE GLYCOL) AND ALPHA-CYCLODEXTRIN
    HARADA, A
    KAMACHI, M
    [J]. MACROMOLECULES, 1990, 23 (10) : 2821 - 2823
  • [8] SYNTHESIS OF A TUBULAR POLYMER FROM THREADED CYCLODEXTRINS
    HARADA, A
    LI, J
    KAMACHI, M
    [J]. NATURE, 1993, 364 (6437) : 516 - 518
  • [9] THE MOLECULAR NECKLACE - A ROTAXANE CONTAINING MANY THREADED ALPHA-CYCLODEXTRINS
    HARADA, A
    LI, J
    KAMACHI, M
    [J]. NATURE, 1992, 356 (6367) : 325 - 327
  • [10] Structures of polyrotaxane models
    Harada, A
    Li, J
    Kamachi, M
    Kitagawa, Y
    Katsube, Y
    [J]. CARBOHYDRATE RESEARCH, 1997, 305 (02) : 127 - 129