Palladium-nickel alloys loaded on tungsten carbide as platinum-free anode electrocatalysts for polymer electrolyte membrane fuel cells

被引:60
作者
Ham, Dong Jin [1 ,2 ,3 ]
Pak, Chanho [3 ]
Bae, Gang Hong [1 ,2 ]
Han, Suenghoon [1 ,2 ]
Kwon, Kyungjung [3 ]
Jin, Seon-Ah [3 ]
Chang, Hyuk [3 ]
Choi, Sun Hee [4 ]
Lee, Jae Sung [1 ,2 ]
机构
[1] Pohang Univ Sci & Technol POSTECH, Dept Chem Engn, Pohang 790784, South Korea
[2] Pohang Univ Sci & Technol POSTECH, Div Adv Nucl Engn, Pohang Accelerator Lab, Pohang 790784, South Korea
[3] Samsung Elect Co LTD, SAIT, Emerging Technol Ctr, Energy Lab, Yongin 446712, Gyounggi Do, South Korea
[4] Pohang Univ Sci & Technol POSTECH, Beamline Res Div, Pohang 790784, South Korea
关键词
CATALYST; OXIDATION; REPLACEMENT; MONOCARBIDE; PD;
D O I
10.1039/c0cc03736b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The strong interaction between PdNi alloys and WC makes PdNi/WC a novel Pt-free electrocatalyst for the anode hydrogen oxidation reaction of polymer electrolyte membrane fuel cells with activity and stability comparable to those of the conventional Pt/C catalysts.
引用
收藏
页码:5792 / 5794
页数:3
相关论文
共 17 条
[1]   A Facile Preparation of Hollow Palladium Nanosphere Catalysts for Direct Formic Acid Fuel Cell [J].
Bai, Zhengyu ;
Yang, Lin ;
Li, Lei ;
Lv, Jing ;
Wang, Kui ;
Zhang, Jie .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (24) :10568-10573
[2]   A class of non-precious metal composite catalysts for fuel cells [J].
Bashyam, Rajesh ;
Zelenay, Piotr .
NATURE, 2006, 443 (7107) :63-66
[3]   Effects of Pb and Mg doping in Al2O3-supported Pd catalyst on direct oxidative esterification of aldehydes with alcohols to esters [J].
Diao, Yanyan ;
Yan, Ruiyi ;
Zhang, Suojiang ;
Yang, Pu ;
Li, Zengxi ;
Wang, Lei ;
Dong, Haifeng .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 303 (1-2) :35-42
[4]   Dependence of PEM fuel cell performance on catalyst loading [J].
Gasteiger, HA ;
Panels, JE ;
Yan, SG .
JOURNAL OF POWER SOURCES, 2004, 127 (1-2) :162-171
[5]   Intermetallics as Novel Supports for Pt Monolayer O2 Reduction Electrocatalysts: Potential for Significantly Improving Properties [J].
Ghosh, Tanushree ;
Vukmirovic, Miomir B. ;
DiSalvo, Francis J. ;
Adzic, Radoslav R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (03) :906-+
[6]   On the possibility of replacement of Pt by Pd in a hydrogen electrode of PEM fuel cells [J].
Grigoriev, S. A. ;
Lyutikova, E. K. ;
Martemianov, S. ;
Fateev, V. N. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (17) :4438-4442
[7]   Pt/WC as an anode catalyst for PEMFC: Activity and CO tolerance [J].
Ham, Dong Jin ;
Kim, Young Kwon ;
Han, Seung Hyun ;
Lee, Jae Sung .
CATALYSIS TODAY, 2008, 132 (1-4) :117-122
[8]   Transition Metal Carbides and Nitrides as Electrode Materials for Low Temperature Fuel Cells [J].
Ham, Dong Jin ;
Lee, Jae Sung .
ENERGIES, 2009, 2 (04) :873-899
[9]   Replacing bulk Pt in Pt-Ni-Pt bimetallic structures with tungsten monocarbide (WC): Hydrogen adsorption and cyclohexene hydrogenation on Pt-Ni-WC [J].
Humbert, Michael P. ;
Menning, Carl A. ;
Chen, Jingguang G. .
JOURNAL OF CATALYSIS, 2010, 271 (01) :132-139
[10]   Electrochemical properties of Pd nanostructures in alkaline solution [J].
Lee, Young-Woo ;
Han, Sang-Beom ;
Park, Kyung-Won .
ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (10) :1968-1971