Synthesis and Structure of Triarylantimony Bis(dihydroxybenzoates)

被引：2

作者：

Sharutin, V. V. ^{[1
]}

Sharutina, O. K. ^{[1
]}

Gubanova, Yu. O. ^{[1
]}

Fominykh, A. S. ^{[1
]}

机构：

[1] Natl Res South Ural State Univ, Chelyabinsk 454080, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2020年 / 90卷 / 01期

关键词：

triarylantimony; dihydroxybenzoic acids; hydrogen peroxide; triarylantimony dicarboxylates; CRYSTAL-STRUCTURE; ORGANOANTIMONY(V);

D O I：

10.1134/S1070363220010168

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the reactions of oxidative addition of 2,6- and 2,3-dihydroxybenzoic acids to triphenyl- and tri(4-methylphenyl)antimony in the presence of hydrogen peroxide as an oxidizing agent, the acids act as monofunctional compounds to form triarylantimony dicarboxylates. Molecular structures of the synthesized compounds were determined by single crystal X-ray diffraction analysis. The tendency of compounds in crystals to dimerization with the formation of intermolecular hydrogen O-HMIDLINE HORIZONTAL ELLIPSISO=C bonds was revealed.

引用

页码：105 / 110

页数：6

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