Long-term performance analysis of an HT-PEM fuel cell based micro-CHP system: Operational strategies

被引:54
作者
Najafi, Behzad [1 ]
Mamaghani, Alireza Haghighat [1 ]
Rinaldi, Fabio [1 ]
Casalegno, Andrea [1 ]
机构
[1] Politecn Milan, Dipartimento Energia, I-20156 Milan, Italy
关键词
Micro cogeneration; High temperature PEM fuel cell; Long term performance; Degradation; Operational strategy; PROTON-EXCHANGE MEMBRANE; WATER-GAS SHIFT; MULTIOBJECTIVE OPTIMIZATION; TEMPERATURE; DEGRADATION; CO; POLYBENZIMIDAZOLE; ELECTROCATALYSTS; MODEL; HEAT;
D O I
10.1016/j.apenergy.2015.03.043
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In the present study, long term performance of an HT-PEM fuel cell based micro CHP system, considering the degradation within the HT-PEM fuel cell stack and the steam methane reformer has been investigated. The variations in the generated electrical and thermal power and the corresponding efficiencies, in the first 15,000 h of operation of the plant, have been studied. Two strategies have been proposed and applied in order to remedy the excursion of thermal and electrical generation of the plant from the steady state production. In the partialization strategy, by means of reducing the fuel fed to the system, the thermal generation of the plant is kept in a specified range. On the other hand, in the recovery strategy, the supplied fuel is gradually increased to suppress the progressive reduction in the power production. The long term performance analysis of the system in normal condition reveals that, due to the degradation within the system, the power production diminishes from 28.2 kW to 23.4 kW while the thermal generation increases from 52.4 kW to 57.5 kW. The results of partialization strategy show that, in order to confine the thermal generation amplification, the partialization factor should be increased up to 7.2%. On the other hand, in the recovery strategy, the supplied fuel should be progressively increased up to 34.2% in order to preserve the electrical output at the initial level. Nevertheless, the recovery strategy has an adverse effect on the electrical efficiency as it diminishes the obtained efficiency to 21.6% compared to 24% obtained for the normal operation. In the last part of the study, the overall performance indexes of the plant, while operating in normal condition and under operational strategies, are compared. It is shown that operating under recovery strategy results in overall electrical efficiency of 24.7% which is notably lower than efficiencies of 26.1% and 26.4% obtained by operating in normal condition and under partialization strategy respectively. However, it was also demonstrated that applying this strategy results in generation of 422.6 MW h of electrical energy which is higher than the values obtained by normal operation (381.3 MW h) and partialization strategy (369.8 MW h). (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:582 / 592
页数:11
相关论文
共 49 条
[1]   Exergetic, economic and environmental (3E) analyses, and multiobjective optimization of a CO2/NH3 cascade refrigeration system [J].
Aminyavari, Mehdi ;
Najafi, Behzad ;
Shirazi, Alec ;
Rinaldi, Fabio .
APPLIED THERMAL ENGINEERING, 2014, 65 (1-2) :42-50
[2]   High temperature PEM fuel cell performance characterisation with CO and CO2 using electrochemical impedance spectroscopy [J].
Andreasen, Soren Juhl ;
Vang, Jakob Rabjerg ;
Kaer, Soren Knudsen .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (16) :9815-9830
[3]  
[Anonymous], 2010, FUNDAMENTALS HEAT MA
[4]   Experimental Characterization of the Poisoning Effects of Methanol-Based Reformate Impurities on a PBI-Based High Temperature PEM Fuel Cell [J].
Araya, Samuel Simon ;
Andreasen, Soren Juhl ;
Kaer, Soren Knudsen .
ENERGIES, 2012, 5 (11) :4251-4267
[5]   Modeling and parametric study of a 1 kWe HT-PEMFC-based residential micro-CHP system [J].
Arsalis, A. ;
Nielsen, Mads P. ;
Kaer, Soren K. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (08) :5010-5020
[6]   Carbon monoxide poisoning of proton exchange membrane fuel cells [J].
Baschuk, JJ ;
Li, XG .
INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2001, 25 (08) :695-713
[7]   Modelling CO poisoning and O2 bleeding in a PEM fuel cell anode [J].
Baschuk, JJ ;
Li, XG .
INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2003, 27 (12) :1095-1116
[8]   Modelling of CO Poisoning and its Dynamics in HTPEM Fuel Cells [J].
Bergmann, A. ;
Gerteisen, D. ;
Kurz, T. .
FUEL CELLS, 2010, 10 (02) :278-287
[9]   Transient simulation of polygeneration systems based on PEM fuel cells and solar heating and cooling technologies [J].
Calise, Francesco ;
Ferruzzi, Gabriele ;
Vanoli, Laura .
ENERGY, 2012, 41 (01) :18-30
[10]   Development of a micro-cogeneration laboratory and testing of a natural gas CHP unit based on PEM fuel cells [J].
Campanari, S. ;
Valenti, G. ;
Macchi, E. ;
Lozza, G. ;
Ravida, N. .
APPLIED THERMAL ENGINEERING, 2014, 71 (02) :714-720