The Electrochemical Stability of Starch Carbon as an Important Property in the Construction of a Lithium-Ion Cell

被引：2

作者：

Kurc, Beata ^{[1
]}

Piglowska, Marita ^{[2
]}

Rymaniak, Lukasz ^{[3
]}

机构：

[1] Poznan Univ Tech, Fac Chem Technol, Inst Chem & Electrochem, Berdychowo 4, PL-60965 Poznan, Poland

[2] Poznan Univ Tech, Fac Chem Technol, Berdychowo 4, PL-60965 Poznan, Poland

[3] Poznan Univ Tech, Fac Civil & Transport Engn, Inst Combust Engines & Powertrains, Piotrowo 3, PL-60965 Poznan, Poland

来源：

ENTROPY | 2021年 / 23卷 / 07期

关键词：

starch; carbon; EIS; Bode plots; SEI; HIGH-PERFORMANCE; ALLOY DESIGN; TEMPERATURE; CAPACITANCE; ELECTRODES; BEHAVIOR; CATHODE;

D O I：

10.3390/e23070861

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

This paper shows use of starch-based carbon (CSC) and graphene as the anode electrode for lithium-ion cell. To describe electrochemical stability of the half-cell system and kinetic parameters of charging process in different temperatures, electrochemical impedance spectroscopy (EIS) measurement was adopted. It has been shown that smaller resistances are observed for CSC. Additionally, Bode plots show high electrochemical stability at higher temperatures. The activation energy for the SEI (solid-electrolyte interface) layer, charge transfer, and electrolyte were in the ranges of 24.06-25.33, 68.18-118.55, and 13.84-15.22 kJ mol(-1), respectively. Moreover, the activation energy of most processes is smaller for CSC, which means that this electrode could serve as an eco-friendly biodegradable lithium-ion cell element.

引用

页数：13

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