Application of molten salts in hydroalkoxycarbonylation of styrene

被引:16
作者
Balázs, A
Benedek, C
Torös, S
机构
[1] Univ Veszprem, Dept Organ Chem, H-8201 Veszprem, Hungary
[2] Richter Gedeon Ltd, Synthet Plant 2, H-2510 Dorog, Hungary
[3] Hungarian Customs & Finance Guard, Inst Chem, H-1163 Budapest, Hungary
基金
匈牙利科学研究基金会; 美国国家科学基金会;
关键词
alkoxycarbonylation; palladium; phosphine; styrene; ionic liquids;
D O I
10.1016/j.molcata.2005.08.048
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydroalkoxycarbonylation of styrene using palladium-based catalyst was studied in quaternary ammonium salts as reaction media. Under the reaction conditions applied, the catalyst-containing phase can be reused several times without a significant decrease in activity and selectivity as a function of the precursor and the halide counter ion used. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:105 / 109
页数:5
相关论文
共 26 条
[1]   THE ALKOXY-ALKOXYCARBONYLATION OF ALLENES [J].
ALPER, H ;
HARTSTOCK, FW ;
DESPEYROUX, B .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (14) :905-906
[2]   PALLADIUM-CATALYZED CONVERSION OF ALKENOLS INTO 5-MEMBERED AND 6-MEMBERED RING LACTONES AT ROOM-TEMPERATURE AND ATMOSPHERIC-PRESSURE [J].
ALPER, H ;
LEONARD, D .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (08) :511-512
[3]   THE REGIOSPECIFIC PALLADIUM CATALYZED HYDROCARBOXYLATION OF ALKENES UNDER MILD CONDITIONS [J].
ALPER, H ;
WOELL, JB ;
DESPEYROUX, B ;
SMITH, DJH .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (21) :1270-1271
[4]  
Beller M., 1998, TRANSITION METALS OR, pI
[5]   A study on the catalytic pathways of the hydroalkoxycarbonylation reaction of styrene [J].
Benedek, C ;
Szalontai, G ;
Gömöry, A ;
Torös, S ;
Heil, B .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 579 (1-2) :147-155
[6]  
CONSIGLIO G, 1976, CHIMIA, V30, P26
[7]   New developments in catalysis using ionic liquids [J].
Gordon, CM .
APPLIED CATALYSIS A-GENERAL, 2001, 222 (1-2) :101-117
[8]   Phospha-palladacycles and N-heterocyclic carbene palladium complexes:: efficient catalysts for CC-coupling reactions [J].
Herrmann, WA ;
Öfele, K ;
Von Preysing, D ;
Schneider, SK .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 687 (02) :229-248
[10]   Clean catalysis with ionic solvents - phosphonium tosylates for hydroformylation [J].
Karodia, N ;
Guise, S ;
Newlands, C ;
Andersen, JA .
CHEMICAL COMMUNICATIONS, 1998, (21) :2341-2342