Efficient removal of naphthalene-2-ol from aqueous solutions by solvent extraction

Naphthalene-2-ol is a typical biologically recalcitrant pollutant in dye wastewater. Solvent extraction of naphthalene-2-ol from aqueous solutions using mixed solvents was investigated. Various extractants and diluents were evaluated, and the effects of volume ratio of extractant to diluent, initial pH, initial concentration of naphthalene-2-ol in aqueous solution, extraction time, temperature, volume ratio of organic phase to aqueous phase (O/A), stirring rate and extraction stages, on extraction efficiency were examined separately. Regeneration and reuse of the spent extractant were also investigated. Results showed that tributyl phosphate (TBP) achieved 98% extraction efficiency for naphthalene-2-ol in a single stage extraction, the highest among the 12 extractants evaluated. Extraction efficiency was optimized when cyclohexane and n-octane were used as diluents. The solvent combination of 20% TBP, 20% n-octanol and 60% cyclohexane (V/V) obtained the maximum extraction efficiency for naphthalene-2-ol, 99.3%, within 20 min using three cross-current extraction stages under the following extraction conditions: O/A ratio of 1:1, initial pH of 3, 25 degrees C and stirring rate of 150 r/min. Recovery of mixed solvents was achieved by using 15% (W/W) NaOH solution at an O:A ratio of 1:1 and a contact time of 15 min. The mixed solvents achieved an extraction capacity for naphthalene-2-ol stably higher than 90% during five cycles after regeneration. (C) 2016 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.