(NHC)CuI (NHC = N-heterocyclic carbene) complexes as efficient catalysts for the reduction of carbonyl compounds

被引：264
|
作者：
Kaur, H [1 ]
Zinn, FK [1 ]
Stevens, ED [1 ]
Nolan, SP [1 ]
机构：
[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA
来源：
ORGANOMETALLICS | 2004年 / 23卷 / 05期
关键词：
D O I：
10.1021/om034285a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hydrosilylation of various ketones is mediated by an imidazolium salt/ Cu(I) salt system or by a well-defined (NHC)CuCl (NHC = N-heterocyclic carbene) catalyst precursor system. Reactions are conducted at room temperature. The synthesis and characterization of well-defined (NHC)CuCl complexes are described.
引用
收藏
页码：1157 / 1160
页数：4
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