Density, Viscosity, and Refractive Index Properties for the Binary Mixtures of n-Butylammonium Acetate Ionic Liquid plus Alkanols at Several Temperatures

被引:64
作者
Xu, Yingjie [1 ,2 ]
Yao, Jia [1 ]
Wang, Congmin [1 ]
Li, Haoran [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
[2] Shaoxing Univ, Dept Chem, Shaoxing 312000, Zhejiang, Peoples R China
基金
美国国家科学基金会;
关键词
EXCESS MOLAR VOLUME; PHYSICAL-PROPERTIES; METHANOL; IMIDAZOLIUM; WATER; ETHANOL; TRIMETHYL-1,4-BENZOQUINONE; 2,3,6-TRIMETHYLPHENOL; TETRAFLUOROBORATE; SEPARATION;
D O I
10.1021/je200707b
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities and viscosities were determined for the binary mixtures of n-butylammonium acetate ionic liquid (N4AC) with methanol, ethanol, n-propanol, and n-butanol at temperatures of (293.15, 298.15, 303.15, 308.15, and 313.15) K under atmospheric pressure. The refractive indices of the above-mentioned binary mixtures were measured at 298.15 K. Excess molar volumes V-E, viscosity deviations Delta eta, and refractive index deviations Delta n(D) were obtained from the experimental data and fitted with the Redlich-Kister equation. The correlation results were in good agreement with the experimental data, and optimal fitting parameters were presented. The results were interpreted in terms of interactions and structural factors of N4AC + alkanols mixtures.
引用
收藏
页码:298 / 308
页数:11
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