Utilisation of a lithium boryl as a reducing agent in low oxidation state group 15 chemistry: synthesis and characterisation of an amido-distibene and a boryl-dibismuthene

被引：62

作者：

Dange, Deepak ^{[1
]}

Davey, Amelia ^{[1
]}

Abdalla, Joseph A. B. ^{[2
]}

Aldridge, Simon ^{[2
]}

Jones, Cameron ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

[2] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 33期

关键词：

ELEMENT; COMPLEXES; CRYSTAL; BI;

D O I：

10.1039/c5cc01772f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first examples of an amido-distibene, L dagger Sb=SbL dagger (L-dagger = -N(Ar dagger)( SiPr3i ), Ar-dagger = C6H2{C(H)Ph-2}(2)Pr-i-2,6,4), and a boryl dibismuthene, {(DAB)B} Bi=Bi{B(DAB)} (DAB = {(C6H3Pr2i-2,6)NCH}(2), have been prepared by reaction of a lithium boryl complex, (THF)(2)LiB(DAB), with extremely bulky amido-group 15 dihalide precursor compounds. In these reactions, the lithium boryl acts as a boryl transfer reagent and/or a strong reducing agent.

引用

页码：7128 / 7131

页数：4

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