Investigation of Salt and precipitating agent effect on the specific surface area and compressive strength of alumina catalyst support

被引:2
作者
Mahmoudian, Mostafa [2 ]
Hemmati, Alireza [1 ]
Hashemabadi, Hasan [2 ]
Ghaemi, Ahad [1 ]
Shahhosseini, Shahrokh [1 ]
机构
[1] Iran Univ Sci & Technol, Dept Chem Oil & Gas Engn, POB 16765-163, Tehran, Iran
[2] Deputy Planning & Technol, Iran Alumina Complex, Jajarm, Iran
关键词
Alumina; Catalyst Support; Sol Gel; Specific Surface Area; Compressive Strength; ORGANIZED MESOPOROUS ALUMINA; NONIONIC SURFACTANTS; TRANSITION ALUMINA; GAMMA-ALUMINA; GAMMA-AL2O3; ADSORPTION; STRATEGIES; STABILITY; OXIDATION; NITROGEN;
D O I
10.1515/pjct-2017-0045
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Nowadays, catalyst supports are extensively used to decrease the costs and increase the contact surface area in chemical reactions. Specific surface area, compressive strength, pore volume and pore size are some of the most important characteristics of a catalyst support. In this work, Sol-gel and peptization methods were applied to produce alumina catalyst support. Also the roles of aluminum salts and precipitating agents on the specific surface area and compressive strength of alumina catalyst support were investigated. In addition, various additives and common methods in the increasing surface area, compressive strength and adjusting the porosity and pore size are used in this study. The results show that using caustic soda as precipitating agent and aluminum chloride salt yields catalyst supports with the best compressive strength. Also, using aluminum nitrate and ammonia as precipitating agent produced alumina catalyst support with the highest specific surface area.
引用
收藏
页码:35 / 40
页数:6
相关论文
共 44 条
[1]   Effect of flash calcined alumina support and potassium doping on the activity of Co-Mo catalysts in sour gas shift process [J].
Antoniak, Katarzyna ;
Kowalik, Pawel ;
Prochniak, Wieslaw ;
Konkol, Marcin ;
Wach, Anna ;
Kustrowski, Piotr ;
Ryczkowski, Janusz .
APPLIED CATALYSIS A-GENERAL, 2012, 423 :114-120
[2]   Hydrogen production by steam reforming of liquefied natural gas (LNG) over ordered mesoporous nickel-alumina catalyst [J].
Bang, Yongju ;
Han, Seung Ju ;
Seo, Jeong Gil ;
Youn, Min Hye ;
Song, Ji Hwan ;
Song, In Kyu .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (23) :17967-17977
[3]  
Becker L. W., 1989, United States Patent, Patent No. [Appl. US4826606 A, 4826606]
[4]  
Bloc J., 1987, United States Patent, Patent No. [Appl. US 4584108 A, 4584108]
[5]   Nanocrystalline mesoporous γ-alumina powders "UPMC1 material" gathers thermal and chemical stability with high surface area [J].
Boissiere, Cedric ;
Nicole, Lionel ;
Gervais, Christelle ;
Babonneau, Florence ;
Antonietti, Markus ;
Amenitsch, Heinz ;
Sanchez, Clement ;
Grosso, David .
CHEMISTRY OF MATERIALS, 2006, 18 (22) :5238-5243
[6]  
Cejka J, 2002, STUD SURF SCI CATAL, V141, P429
[7]  
Cejka J, 2001, PHYS CHEM CHEM PHYS, V3, P5076
[8]   Sol-gel based alumina powders with catalytic applications [J].
Crisan, Maria ;
Zaharescu, Maria ;
Kumari, Valluri Durga ;
Subrahmanyam, Machiraju ;
Crisan, Dorel ;
Dragan, Nicolae ;
Raileanu, Malina ;
Jitianu, Mihaela ;
Rusu, Adriana ;
Sadanandam, Gullapelli ;
Reddy, Jakkidi Krishna .
APPLIED SURFACE SCIENCE, 2011, 258 (01) :448-455
[9]   Modeling the effects of calcination conditions on the physical and chemical properties of transition alumina catalysts [J].
Da Ros, Simoni ;
Barbosa-Coutinho, Elisa ;
Schwaab, Marcio ;
Calsavara, Valmir ;
Fernandes-Machado, Nadia R. C. .
MATERIALS CHARACTERIZATION, 2013, 80 :50-61
[10]   Characterization of mesoporous alumina molecular sieves synthesized by nonionic templating [J].
Deng, W ;
Bodart, P ;
Pruski, M ;
Shanks, BH .
MICROPOROUS AND MESOPOROUS MATERIALS, 2002, 52 (03) :169-177