50th Anniversary Perspective: RAFT Polymerization-A User Guide

被引：1156

作者：

Perrier, Sebstien ^{[1
,2
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[2] Monash Univ, Fac Pharm & Pharmaceut Sci, 381 Royal Parade, Parkville, Vic 3052, Australia

来源：

MACROMOLECULES | 2017年 / 50卷 / 19期

关键词：

FRAGMENTATION-CHAIN-TRANSFER; LIVING RADICAL POLYMERIZATION; END-GROUP REMOVAL; BLOCK-COPOLYMERS; MULTIBLOCK COPOLYMERS; MOLECULAR-WEIGHT; CATIONIC-POLYMERIZATION; DIBLOCK COPOLYMERS; CONTROLLED GROWTH; VINYL-ACETATE;

D O I：

10.1021/acs.macromol.7b00767

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This Perspective summarizes the features and limitations of reversible addition-fragmentation chain transfer (RAFT) polymerization, highlighting its strengths and weaknesses, as our understanding of the process, from both a mechanistic and an application point of view, has matured over the past 20 years. It is aimed at both experts in the field and newcomers, including undergraduate and postgraduate students, as well as nonexperts in polymerization who are interested in developing their own polymeric structures by exploiting the simple setup of a RAFT polymerization.

引用

页码：7433 / 7447

页数：15

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