Synthesis and characterization of the first pentaphenylcyclopentadienyl copper(I) complex, (Ph5Cp)Cu(PPh3)

被引：14
作者：
Anderson, QT [1 ]
Erkizia, E [1 ]
Conry, RR [1 ]
机构：
[1] Univ Nevada, Dept Chem 216, Reno, NV 89557 USA
来源：
ORGANOMETALLICS | 1998年 / 17卷 / 22期
关键词：
D O I：
10.1021/om980569x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
(Ph5Cp)Cu(PPh3) (1) has been, synthesized fi om Na[Ph5Cp] and [(PPh3)CuCl](4). Complex 1 is the first reported pentaphenylcyclopentadienyl -copper complex and is a rare example of a pi-bound Cu-Cp complex. Complex I has been fully characterized, including crystallographically;the P-31 NMR chemical shift for the triphenylphosphine ligand in 1 appears unusually far downfield for a Cu(I)-PPh3 complex, at +23.2 ppm.
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页码：4917 / 4920
页数：4
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