Synthesis and characterization of the first pentaphenylcyclopentadienyl copper(I) complex, (Ph5Cp)Cu(PPh3)

被引：14

作者：

Anderson, QT ^{[1
]}

Erkizia, E ^{[1
]}

Conry, RR ^{[1
]}

机构：

[1] Univ Nevada, Dept Chem 216, Reno, NV 89557 USA

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 22期

关键词：

D O I：

10.1021/om980569x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(Ph5Cp)Cu(PPh3) (1) has been, synthesized fi om Na[Ph5Cp] and [(PPh3)CuCl](4). Complex 1 is the first reported pentaphenylcyclopentadienyl -copper complex and is a rare example of a pi-bound Cu-Cp complex. Complex I has been fully characterized, including crystallographically;the P-31 NMR chemical shift for the triphenylphosphine ligand in 1 appears unusually far downfield for a Cu(I)-PPh3 complex, at +23.2 ppm.

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页码：4917 / 4920

页数：4

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