Stepwise Cyanation of Naphthalene Diimide for n-Channel Field-Effect Transistors

被引：89

作者：

Chang, Jingjing ^{[1
]}

Ye, Qun ^{[1
]}

Huang, Kuo-Wei ^{[2
,3
]}

Zhang, Jie ^{[4
]}

Chen, Zhi-Kuan ^{[4
]}

Wu, Jishan ^{[1
,4
]}

Chi, Chunyan ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[2] 4700 King Abduliah Univ Sci & Technol, KAUST Catalysis Ctr, Thuwal 239556900, Saudi Arabia

[3] 4700 King Abduliah Univ Sci & Technol, Div Chem & Life Sci & Engn, Thuwal 239556900, Saudi Arabia

[4] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 12期

关键词：

SEMICONDUCTORS; TRANSPARENT; PERFORMANCE; ELECTRON;

D O I：

10.1021/ol300914k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stepwise cyanation of tetrabromonaphthalenediimide (NDI) 1 gave a series of cyanated NDIs 2-5 with the monocyanated NDI 2 and dicyanated NDI 3 isolated. The tri- and tetracyano- NDIs 4 and 5 show intrinsic instability toward moisture because of their extremely low-lying LUMO energy levels. The partially cyanated intermediates can be utilized as air-stable n-type semiconductors with OFET electron mobility up to 0.05 cm(2) V-1 s(-1).

引用

页码：2964 / 2967

页数：4

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