The novel linear-polymeric organolithium compound {(Me(2)NMe(2)Si)(3)CLi}(infinity)

被引：13

作者：

Adam, F ^{[1
]}

Eaborn, C ^{[1
]}

Hitchcock, PB ^{[1
]}

Smith, JD ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 06期

关键词：

D O I：

10.1039/cc9960000741

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound (Me(2)NMe(2)Si)(3)CH is readily metallated by MeLi in THF to give the linear-polymeric {(Me(2)NMe(2)Si)(3)CLi}(infinity), in which two of the N atoms in each planar carbanionic unit (Me(2)NMe(2)SiC- are attached to one lithium atom and the remaining N atom to another Li atom; each Li shows planar three-coordination.

引用

页码：741 / 742

页数：2

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