An approach of estimating struvite growth kinetic incorporating thermodynamic and solution chemistry, kinetic and process description

被引:59
作者
Ali, Md. Imtiaj [1 ]
Schneider, Philip Andrew [2 ]
机构
[1] Earth Tech Engn Pty Ltd, Brisbane, QLD 4006, Australia
[2] James Cook Univ, Sch Engn, Townsville, QLD 4811, Australia
关键词
struvite; growth model; thermodynamic; kinetic; process; kinetic estimation;
D O I
10.1016/j.ces.2008.04.023
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Discharge of untreated nutrient-rich wastewater is a problematic issue, which may cause root burning and the eutrophication of receiving water. It is also a problematic issue due to the formation of crystalline deposits in waste water systems. The recovery of nutrient using crystallization technique may provide a value added product. The recovered product is struvite, which is chemically known as magnesium ammonium phosphate hexahydrates. The key focus of this paper is the modeling and simulation of struvite growth, incorporating solution chemistry and thermodynamics, growth kinetic and process description of the recovery system. An ensemble of experimental data is combined with the dynamic model to estimate struvite growth kinetics. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3514 / 3525
页数:12
相关论文
共 20 条
[1]   A fed-batch design approach of struvite system in controlled supersaturation [J].
Ali, Md. Imtiaj ;
Schneider, Philip Andrew .
CHEMICAL ENGINEERING SCIENCE, 2006, 61 (12) :3951-3961
[2]  
ALKHAYAT A, 1990, 11 S IND CRYST GARM
[3]  
ALLISON J.D., 1991, MINTEQA2 PRODEFA2 GE
[4]   Spontaneous precipitation of struvite from aqueous solutions [J].
Bouropoulos, NC ;
Koutsoukos, PG .
JOURNAL OF CRYSTAL GROWTH, 2000, 213 (3-4) :381-388
[6]   Influence of crystal habit on the compression and densification mechanism of ibuprofen [J].
Di Martino, P ;
Beccerica, M ;
Joiris, E ;
Palmieri, GF ;
Gayot, A ;
Martelli, S .
JOURNAL OF CRYSTAL GROWTH, 2002, 243 (02) :345-355
[7]  
Draper NR., 1966, APPL REGRESSION ANAL
[8]  
*GPROMS, 2002, GPROMS ADV US GUID
[9]  
Mandel J., 2012, The Statistical Analysis of Experimental Data
[10]  
Martell A. E., 1989, CRITICAL STABILITY C