Vanadia-catalyzed solar photooxidation of aniline

被引：38

作者：

Karunakaran, C ^{[1
]}

Senthilvelan, S ^{[1
]}

机构：

[1] Annamalai Univ, Dept Chem, Annamalainagar 608002, Tamil Nadu, India

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2005年 / 289卷 / 02期

关键词：

photooxidation; aniline; sunlight; UV light; V2O5;

D O I：

10.1016/j.jcis.2005.03.071

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vanadia photocatalyzes the oxidation of aniline to azobenzene in ethanol. The reaction was studied using natural sunlight and UV irradiation (365 nm) as a function of [aniline], catalyst loading, airflow rate, solvent composition, etc. The photocatalyst exhibits sustainable catalytic activity. The product formation is greater with illumination at 254 nm than at 365 nm. Electron donors such as triphenylphosphine, diphenylamine, and hydroquinone enhance the photocatalysis. The singlet oxygen quencher azide ion fails to inhibit the catalysis. The photocatalysis takes place in both protic and aprotic solvents. The mechanism of photocatalysis is discussed and the product formation analyzed using a kinetic model. (c) 2005 Elsevier Inc. All rights reserved.

引用

页码：466 / 471

页数：6

共 17 条

[1] Photocatalytic destruction of potassium hydrogen phthalate using TiO2 and sunlight:: application for the treatment of industrial wastewater [J].

Alhakimi, G ;

Studnicki, LH ;

Al-Ghazali, M .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 154 (2-3) :219-228

[2] PHOTOREACTIONS OF AROMATIC CARBONYL-COMPOUNDS WITH AMINES .2. REACTIONS OF TRIPLET BENZOPHENONE AND OTHER KETONES WITH PRIMARY AND SECONDARY AROMATIC-AMINES [J].

DAVIDSON, RS ;

LAMBETH, PF ;

SANTHANA.M .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1972, (15) :2351-2355

[3] Unusual photoreactivity of zinc oxide irradiated by concentrated sunlight [J].

Dindar, B ;

Içli, S .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 140 (03) :263-268

[4]

HEMA MA, 1977, INDIAN J CHEM B, V15, P947

[5] Relationship between the yields of products from ethanol over titanium dioxide and the quantity of light [J].

Iseda, K ;

Towata, A ;

Watanabe, E ;

Fukaya, M ;

Taoda, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (05) :1249-1253

[6] Fluorescence emission and photooxidation studies with 5,6-and 6,7-benzocoumarins and a 5,6-benzochromone under direct and concentrated sun [J].

Karapire, C ;

Kolancilar, H ;

Oyman, Ü ;

Icli, S .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 153 (1-3) :173-184

[7] Photooxidation of iodide ion on some semiconductor and non-semiconductor surfaces [J].

Karunakaran, C ;

Senthilvelan, S ;

Karuthapandian, S ;

Balaraman, K .

CATALYSIS COMMUNICATIONS, 2004, 5 (06) :283-290

[8]

KASTURIRANGAN H, 1981, INDIAN J TECHNOL, V19, P327

[9] PHOTOSENSITIZED REACTIONS OF TOLUIDINES ON ZINC-OXIDE [J].

KASTURIRANGAN, H ;

RAMAKRISHNAN, V ;

KURIACOSE, JC .

JOURNAL OF CATALYSIS, 1981, 69 (01) :216-217

[10]

Leng WH, 2000, J PHOTOCH PHOTOBIO A, V131, P125

← 1 2 →