Rhodium(III)-Catalyzed C-H/N-H Functionalization with Hydrogen Evolution

被引：6
作者：
Xie, Hui [1 ]
Jiang, Jijun [1 ]
Wang, Jun [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem, Minist Educ, Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2020年 / 26卷 / 33期
基金：
中国国家自然科学基金;
关键词：
C-H activation; hydrogen evolution; isoquinolin-3-ols; redox neutral; rhodium(III) catalysis; RHODIUM-CATALYZED ANNULATION; BETA-PHENYLETHYLAMINES; SELECTIVE SYNTHESIS; ORTHO-ALKENYLATION; IRIDIUM COMPLEXES; INTERNAL ALKYNES; BOND ACTIVATION; EASY ACCESS; ISOQUINOLINES; ACTIVATION/ANNULATION;
D O I：
10.1002/chem.202000950
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A rhodium(III)-catalyzed C-H/N-H bond functionalization of benzimidates with alpha-chloroaldehydes to afford isoquinolin-3-ol derivatives is reported. No external oxidants are needed in this process, and interestingly, evolution of hydrogen gas is observed.
引用
收藏
页码：7365 / 7368
页数：4
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