Synthesis and crystal structures of copper(I) iodide complexes chelating with bis(ethylamidophosphine)

被引：17

作者：

Li, Y ^{[1
]}

Yung, KF ^{[1
]}

Chan, HS ^{[1
]}

Wong, WT ^{[1
]}

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 12期

关键词：

copper(I) iodide complex; bis(ethylamidophosphine); cubane; crystal structure;

D O I：

10.1016/j.inoche.2003.09.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two copper(I) iodide complexes with polydentate bis(ethylamidophosphine) ligands were synthesized, characterized with crystal structures. They include a dimeric complex [Cu(mu-I)(CH2NHCOC2H4PPh2)(2)](2) 1 containing a planar Cu2I2 rhombohedron with two doubly bridged ligands and a tetrameric complex {Cu-4(mu-I)(4)[(CH2NHCOC2H4PPh2)(2)](2)} 3 with all the coppers and iodines forming a highly distorted cubane geometry. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：1451 / 1453

页数：3

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