Synthesis, structure, fluorescence, electrochemical, and antioxidant studies of a new silver(I) complex with 2,6-bis(N-methylbenzimidazol-2-yl)pyridine

被引:7
作者
Xia, Lixian [1 ]
Xia, Xinzhao [1 ]
Zhang, Geng [1 ]
Wu, Yancong [1 ]
Wu, Huilu [1 ]
Xu, Jianhua [1 ]
机构
[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China
关键词
antioxidant; crystal structure; fluorescence; silver(I) complex; supramolecular interactions; DNA-BINDING PROPERTIES; PI-PI-INTERACTION; V-SHAPED LIGAND; X-RAY-STRUCTURE; CRYSTAL-STRUCTURE; NICKEL(II) COMPLEXES; COPPER(II); MANGANESE(II); AG(I);
D O I
10.1177/1747519820978588
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new silver(I) complex of the type [Ag-2(mbbp)(2)](pic)(2)center dot DMF center dot CH3OH [mbbp = 2,6-bis(N-methylbenzimidazol-2-yl)pyridine] is synthesized and analyzed using a range of spectroscopic and crystallographic techniques. This compound contains cationic Ag-2(mbbp)(2) dimers, in which the crossed eight-shaped structure is formed by two mbbp ligands bridging two silver(I) centers and Ag-Ag bonds. Two-dimensional supramolecular networks of the silver(I) complex are connected by pi center dot center dot center dot pi interactions and hydrogen bonds. Hirshfeld analyses are performed to support the aforementioned intermolecular interactions. The effect of pi center dot center dot center dot pi stacking interactions on the fluorescence properties of the complex is investigated. Cyclic voltammetry indicates two irreversible redox processes. In addition, an antioxidant assay in vitro demonstrates that the silver(I) complex displays excellent scavenging activity toward hydroxyl radicals.
引用
收藏
页码:608 / 614
页数:7
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