Damage reduction and sealing of low-k films by combined He and NH3 plasma treatment

被引:32
作者
Urbanowicz, A. M. [1 ]
Baklanov, M. R. [1 ]
Heijlen, J. [1 ]
Travaly, Y. [1 ]
Cockburn, A. [1 ]
机构
[1] IMEC, Louvain, Belgium
关键词
LOW DIELECTRIC-CONSTANT; RADIATION;
D O I
10.1149/1.2760189
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Modification of chemical vapor deposition low-k films upon sequential exposure to helium plasma and then ammonia plasma is characterized using various methods. The He plasma emits extreme ultraviolet (EUV) photons creating O-2 vacancies, which impacts surface reactive sites and induces localized chemical modifications in the first surface monolayers. The subsequent NH3 plasma treatment provides complete sealing of the low-k surface. The depth of the modification, which is a factor of merit of the sealing process, is limited because of the high absorption coefficient of silica-based low-k materials in the range of EUV emission. (C) 2007 The Electrochemical Society.
引用
收藏
页码:G76 / G79
页数:4
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