Long-range interactions between alkali Rydberg atom pairs correlated to the ns-ns, np-np and nd-nd asymptotes

被引:249
作者
Singer, K
Stanojevic, J
Weidemüller, M
Côté, R
机构
[1] Univ Freiburg, Phys Inst, D-79104 Freiburg, Germany
[2] Univ Connecticut, U 3046, Storrs, CT 06269 USA
关键词
D O I
10.1088/0953-4075/38/2/021
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We have calculated the long-range interaction potential curves of highly excited Rydberg atom pairs for the combinations Li-Li, Na-Na, K-K, Rb-Rb and Cs-Cs in a perturbative approach. The dispersion C-coefficients are determined for all symmetries of molecular states that correlate to the ns-ns, np-np and nd-nd asymptotes. Fitted parameters are given for the scaling of the C-coefficients as a function of the principal quantum number n for all homonuclear pairs of alkali metal atoms.
引用
收藏
页码:S295 / S307
页数:13
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