Facet-dependent NiS2 polyhedrons on counter electrodes for dye-sensitized solar cells

被引：86

作者：

Zheng, Jinlong ^{[1
]}

Zhou, Wei ^{[1
]}

Ma, Yiran ^{[1
]}

Cao, Wei ^{[1
]}

Wang, Chengbo ^{[1
]}

Guo, Lin ^{[1
]}

机构：

[1] Beihang Univ, Sch Chem & Environm, Beijing 100191, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 64期

基金：

中国国家自然科学基金;

关键词：

IN-SITU SYNTHESIS; LOW-COST; HIGH-EFFICIENCY; GRAPHENE OXIDE; NANOPARTICLES; NANOCOMPOSITE; REDUCTION; SULFIDE; CATHODE; FILMS;

D O I：

10.1039/c5cc03890a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Octahedral and cubic NiS2 nanocrystals enclosed by {111} and {100} planes were separately used as counter electrodes (CEs) incorporated into Pt-free dye-sensitized solar cells (DSSCs). The DSSC assembled by NiS2 octahedrons exhibited a conversion efficiency of 5.98%, better than that by NiS2 cubes (5.43%). DFT calculations indicate that the better catalytic effect could be ascribed to higher surface energy, more active sites, and more suitable adsorption energy of {111} planes compared with the {100} planes.

引用

页码：12863 / 12866

页数：4

共 32 条

[1] A quasi core-shell nitrogen-doped graphene/cobalt sulfide conductive catalyst for highly efficient dye-sensitized solar cells
Bi, Enbing
Chen, Han
Yang, Xudong
Peng, Wenqin
Graetzel, Michael
Han, Liyuan
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (08) : 2637 - 2641
[2] Ionization of High-Density Deep Donor Defect States Explains the Low Photovoltage of Iron Pyrite Single Crystals
Caban-Acevedo, Miguel
Kaiser, Nicholas S.
English, Caroline R.
Liang, Dong
Thompson, Blaise J.
Chen, Hong-En
Czech, Kyle J.
Wright, John C.
Hamers, Robert J.
Jin, Song
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (49) : 17163 - 17179
[3] Synthesis, Characterization, and Variable Range Hopping Transport of Pyrite (FeS2) Nanorods, Nanobelts, and Nanoplates
Caban-Acevedo, Miguel
Liang, Dong
Chew, Kit S.
DeGrave, John P.
Kaiser, Nicholas S.
Jin, Song
[J]. ACS NANO, 2013, 7 (02) : 1731 - 1739
[4] Synthesis and Properties of Semiconducting Iron Pyrite (FeS2) Nanowires
Caban-Acevedo, Miguel
Faber, Matthew S.
Tan, Yizheng
Hamers, Robert J.
Jin, Song
[J]. NANO LETTERS, 2012, 12 (04) : 1977 - 1982
[5] Nanoarchitecture of variable sized graphene nanosheets incorporated into three-dimensional graphene network for dye sensitized solar cells
Chang, Quanhong
Huang, Lei
Wang, Jinzhong
Ma, Zhoujing
Li, Panpan
Yan, Yuan
Zhu, Jianxiao
Xu, Shuhua
Shen, Leo
Chen, Qi
Yu, Qingjiang
Shi, Wangzhou
[J]. CARBON, 2015, 85 : 185 - 193
[6] Gram-Scale Synthesis of Catalytic Co S Nanocrystal Ink as a Cathode Material for Spray-Deposited, Large-Area Dye-Sensitized Solar Cells
Chang, Shu-Hao
Lu, Ming-De
Tung, Yung-Liang
Tuan, Hsing-Yu
[J]. ACS NANO, 2013, 7 (10) : 9443 - 9451
[7] Elucidation of electrochemical properties of electrolyte-impregnated micro-porous ceramic films as framework supports in dye-sensitized solar cells
Chen, Hseng Shao
Lue, Shingjiang Jessie
Tung, Yung Liang
Cheng, Kong Wei
Huang, Fu Yuan
Ho, Kuo Chuan
[J]. JOURNAL OF POWER SOURCES, 2011, 196 (08) : 4162 - 4172
[8] Novel PtO decorated MWCNTs as a highly efficient counter electrode for dye-sensitized solar cells
Chen, Xiao
Guo, Jian Wei
Hou, Yu
Li, Yu Hang
Yang, Shuang
Zheng, Li Rong
Zhang, Bo
Yang, Xiao Hua
Yang, Hua Gui
[J]. RSC ADVANCES, 2015, 5 (11): : 8307 - 8310
[9] Low-cost SnSx counter electrodes for dye-sensitized solar cells
Chen, Xiao
Hou, Yu
Zhang, Bo
Yang, Xiao Hua
Yang, Hua Gui
[J]. CHEMICAL COMMUNICATIONS, 2013, 49 (51) : 5793 - 5795
[10] Transparent Metal Selenide Alloy Counter Electrodes for High-Efficiency Bifacial Dye-Sensitized Solar Cells
Duan, Yanyan
Tang, Qunwei
Liu, Juan
He, Benlin
Yu, Liangmin
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (52) : 14569 - 14574

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