Synthesis, separation and NMR spectral analysis of methyl apiofuranosides

被引：72
作者：
Ishii, T
Yanagisawa, M
机构：
[1] Forestry & Forest Prod Res Inst, Tsukuba, Ibaraki 3058678, Japan
[2] Shimadzu Analyt & Measuring Ctr, Nakagyo Ku, Kyoto 604, Japan
来源：
CARBOHYDRATE RESEARCH | 1998年 / 313卷 / 3-4期
关键词：
apiose; 3-C-(hydroxymethyl)-D-glycero-aldotetrose; methyl apiofuranosides;
D O I：
10.1016/S0008-6215(98)00262-6
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Methyl apiofuranosides were prepared by methanolysis of D-apiose. Four methyl apiofuranosides were separated by ion-exclusion and normal phase chromatography and their structures were characterized by H-1 and C-13 NMR spectroscopy. The composition of methyl apiofuranosides was almost the same as that of D-apiose in D2O. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：189 / 192
页数：4
相关论文
共 10 条
[1]   COMPLEXES OF CARBOHYDRATES WITH METAL-CATIONS .9. SYNTHESIS OF METHYL D-TAGATOSIDES, D-PSICOSIDES, D-APIOSIDES AND D-ERYTHROSIDES [J].
ANGYAL, SJ ;
BODKIN, CL ;
MILLS, JA ;
POJER, PM .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1977, 30 (06) :1259-1268
[2]  
Beck E., 1990, Methods in Plant Biochemistry, Vol. 2: Carbohydrates., P235
[3]   Isolation and characterization of a boron-rhamnogalacturonan-II complex from cell walls of sugar beet pulp [J].
Ishii, T ;
Matsunaga, T .
CARBOHYDRATE RESEARCH, 1996, 284 (01) :1-9
[4]   Oligosaccharides generated by partial hydrolysis of the borate-rhamnogalacturonan II complex from sugar beet [J].
Ishii, T ;
Kaneko, S .
PHYTOCHEMISTRY, 1998, 49 (05) :1195-1202
[5]   A boron-rhamnogalacturonan-II complex from bamboo shoot cell walls [J].
Kaneko, S ;
Ishii, T ;
Matsunaga, T .
PHYTOCHEMISTRY, 1997, 44 (02) :243-248
[6]   Two chains of rhamnogalacturonan II are cross-linked by borate-diol ester bonds in higher plant cell walls [J].
Kobayashi, M ;
Matoh, T ;
Azuma, J .
PLANT PHYSIOLOGY, 1996, 110 (03) :1017-1020
[7]  
O'Neill M., 1990, Methods in Plant Biochemistry, P415, DOI [10.1016/B978-0-12-461012-5.50018-5, DOI 10.1016/B978-0-12-461012-5.50018-5]
[8]   Rhamnogalacturonan-II, a pectic polysaccharide in the walls of growing plant cell, forms a dimer that is covalently cross-linked by a borate ester - In vitro conditions for the formation and hydrolysis of the dimer [J].
ONeill, MA ;
Warrenfeltz, D ;
Kates, K ;
Pellerin, P ;
Doco, T ;
Darvill, AG ;
Albersheim, P .
JOURNAL OF BIOLOGICAL CHEMISTRY, 1996, 271 (37) :22923-22930
[9]   Structural characterization of red wine rhamnogalacturonan II [J].
Pellerin, P ;
Doco, T ;
Vidal, S ;
Williams, P ;
Brillouet, JM ;
ONeill, MA .
CARBOHYDRATE RESEARCH, 1996, 290 (02) :183-197
[10]   DL-APIOSE SUBSTITUTED WITH STABLE ISOTOPES - SYNTHESIS, NMR-SPECTRAL ANALYSIS, AND FURANOSE ANOMERIZATION [J].
SNYDER, JR ;
SERIANNI, AS .
CARBOHYDRATE RESEARCH, 1987, 166 (01) :85-99
1