Internal Functionalization of Three-Dimensional Covalent Organic Frameworks

被引：203

作者：

Bunck, David N. ^{[1
]}

Dichtel, William R. ^{[1
]}

机构：

[1] Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 08期

关键词：

covalent organic frameworks; crystal engineering; microporous materials; polymers; self-assembly; CRYSTALLINE; ACTIVATION;

D O I：

10.1002/anie.201108462

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thinking inside the COF: Internally functionalized, boroxine-linked, three-dimensional, covalent organic frameworks (COFs) can be synthesized by co-crystallizing a truncated, trifunctional monomer with the parent tetrafunctional building block. The functionalized COFs possess accessible functional groups and a distinct interior microenvironment. In the picture the orange sphere corresponds to an alkyl chain or an allyl group in the pore interior. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1885 / 1889

页数：5

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