Recent Progress in the Research of the Transition-Metal-Catalyzed N-Directed Carbonyl and Alcohol Hydroxyl ortho C-C Bonds Activation Reactions

被引:9
作者
Wang, Jingjing [1 ]
Li, Feng [1 ]
Yu, Xiaobo [3 ]
Liu, Lantao [1 ]
Ding, Junru [1 ]
Xie, Peiyao [1 ]
Wang, Jianhui [2 ]
机构
[1] Shangqiu Normal Univ, Sch Chem & Chem Engn, Henan Engn Lab Green Synth Pharmaceut, Shangqiu 476000, Peoples R China
[2] Tianjin Univ, Dept Chem, Coll Sci, Tianjin 300072, Peoples R China
[3] Jilin Inst Chem Technol, Coll Mat Sci & Engn, Jilin 132022, Jilin, Peoples R China
关键词
C-C bond activation; reductive elimination; transition metals; metalation; COOPERATIVE CATALYSIS; UNSTRAINED KETONE; BENZOIC-ACIDS; ARYL KETONES; CLEAVAGE; RHODIUM; DECARBONYLATION; ALLYLAMINES; ARYLATION; EXCHANGE;
D O I
10.6023/cjoc201802007
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Transition-metal-catalyzed C-C bond cleavage has been considered as one of the most interesting subject and challenging area in organometallic chemistry. The recent progress of transition-metal-catalyzed (Rh, Ni, Pd and Ru) nitrogen atom chelation-assisted C-C activation and controlled transformation is reviewed, and the mechanisms of these C-C activation reactions are also discussed.
引用
收藏
页码:1638 / 1649
页数:12
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