Vapor phase hydrogenation of furfural to furfuryl alcohol over environmentally friendly Cu-Ca/SiO2 catalyst

被引：135

作者：

Wu, J ^{[1
]}

Shen, YM

Liu, CH

Wang, HB

Geng, C

Zhang, ZX

机构：

[1] Dalian Univ Technol, Sch Chem Engn, Dalian 116012, Peoples R China

[2] Shenyang Inst Chem Technol, Sch Chem Engn, Shenyang 110142, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2005年 / 6卷 / 09期

关键词：

Cu-Ca/SiO2; furfural; hydrogenation; furfuryl alcohol;

D O I：

10.1016/j.catcom.2005.06.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Cu-Ca/SiO2 catalysts were prepared by sol-gel and impregnation methods, respectively. A comparative study on their structures has been carried out by XRD, BET, chemisorption of nitrous oxide and XPS techniques. The catalytic performance of two catalysts for vapor phase hydrogenation of furfural to furfuryl alcohol was tested. Compared with the Cu-Ca/SiO2 catalyst prepared by impregnation method, the Cu-Ca/SiO2 catalyst prepared by sol-gel technique showed higher copper dispersion and higher activity. In addition, both catalysts revealed high selectivity in hydrogenation of furfural to furfuryl alcohol. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：633 / 637

页数：5

共 20 条

[1] AN IMPROVED PROCEDURE FOR ESTIMATING THE METAL-SURFACE AREA OF SUPPORTED COPPER-CATALYSTS
BOND, GC
NAMIJO, SN
[J]. JOURNAL OF CATALYSIS, 1989, 118 (02) : 507 - 510
[2] Chen XF, 2002, APPL CATAL A-GEN, V233, P13
[3] CONG Y, 2000, CHINESE J CATAL, V21, P314
[4] Cu/SiO2 catalysts for methanol to methyl formate dehydrogenation -: A comparative study using different preparation techniques
Guerreiro, ED
Gorriz, OF
Larsen, G
Arrúa, LA
[J]. APPLIED CATALYSIS A-GENERAL, 2000, 204 (01) : 33 - 48
[5] Characterization of Ca-promoted Ni/α-Al2O3 catalyst for CH4 reforming with CO2
Hou, ZY
Yokota, O
Tanaka, T
Yashima, T
[J]. APPLIED CATALYSIS A-GENERAL, 2003, 253 (02) : 381 - 387
[6] Reforming of CH4 with CO2 and O2 to produce syngas over CaO modified Ni/SiO2 catalysts in a fluidized bed reactor
Jing, QS
Lou, H
Mo, LY
Fei, JH
Zheng, XM
[J]. REACTION KINETICS AND CATALYSIS LETTERS, 2004, 83 (02): : 291 - 298
[7] Platinum deposited on monolayer supports in selective hydrogenation of furfural to furfuryl alcohol
Kijenski, J
Winiarek, P
Paryjczak, T
Lewicki, A
Mikolajska, A
[J]. APPLIED CATALYSIS A-GENERAL, 2002, 233 (1-2) : 171 - 182
[8] Selective hydrogenation of furfural on Ni-P, Ni-B, and Ni-P-B ultrafine materials
Lee, SP
Chen, YW
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1999, 38 (07) : 2548 - 2556
[9] Effects of preparation on the catalytic properties of Ni-P-B ultrafine materials
Lee, SP
Chen, YW
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (06) : 1495 - 1499
[10] Liquid phase hydrogenation of furfural to furfuryl alcohol over the Fe-promoted Ni-B amorphous alloy catalysts
Li, HX
Luo, HS
Zhuang, L
Dai, WL
Qiao, MH
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 203 (1-2) : 267 - 275

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