Cellulose nanocrystals reinforced foamed nitrile rubber nanocomposites

被引:36
作者
Chen, Yukun [1 ,3 ]
Zhang, Yuanbing [1 ,3 ]
Xu, Chuanhui [1 ,2 ,3 ]
Cao, Xiaodong [3 ,4 ]
机构
[1] S China Univ Technol, State Key Lab Pulp & Paper Engn China, Guangzhou 510640, Guangdong, Peoples R China
[2] Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
[3] S China Univ Technol, Minist Educ, Key Lab Polymer Proc Engn, Guangzhou 510640, Guangdong, Peoples R China
[4] S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China
关键词
Cellulose nanocrystals; Foamed rubber; Reinforce; Nanocomposites; BLEND-BASED FOAM; MECHANICAL-PROPERTIES; MAGNESIUM METHACRYLATE; MICROCELLULAR FOAMS; PHYSICAL-PROPERTIES; NATURAL-RUBBER; COMPOSITES; COPOLYMER; PRETREATMENT; BIOMASS;
D O I
10.1016/j.carbpol.2015.05.017
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Research on foamed nitrile rubber (NBR)/cellulose nanocrystals (CNs) nanocomposites is rarely found in the literatures. In this paper, CNs suspension and NBR latex was mixed to prepared the foamed NBR/CNs nanocomposites. We found that the CNs mainly located in the cell walls, effectively reinforcing the foamed NBR. The strong interaction between the CNs and NBR matrix restricted the mobility of NBR chains surrounding the CNs, hence increasing the crosslink density of the NBR matrix. CNs exhibited excellent reinforcement on the foamed NBR: a remarkable increase nearly 76% in the tensile strength of the foamed nanocomposites was achieved with a load of only 15 phr CNs. Enhanced mechanical properties make the foamed NBR/CNs nanocomposites a promising damping material for industrial applications with a potential to reduce the petroleum consumption. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:149 / 154
页数:6
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