Synthesis, optical properties and singlet oxygen generation of a phthalocyanine derivative containing strong two-photon-absorbing chromophores in the periphery

被引：8

作者：

Liu, Zijun ^{[1
]}

Xiong, Xiaoqin ^{[2
]}

Li, Yu ^{[1
]}

Li, Suyue ^{[1
]}

Qin, Jingui ^{[1
]}

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

[2] Xinyang Normal Univ, Dept Chem & Chem Engn, Xinyang 464000, Henan, Peoples R China

来源：

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES | 2011年 / 10卷 / 11期

基金：

中国国家自然科学基金;

关键词：

2-PHOTON PHOTOSENSITIZED PRODUCTION; CONJUGATED PORPHYRIN DIMERS; ABSORPTION CROSS-SECTIONS; RESONANCE ENERGY-TRANSFER; ENHANCEMENT; SENSITIZERS; EXCITATION;

D O I：

10.1039/c1pp05166k

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A phthalocyanine derivative containing two-photon chromophores which are based on pyrimidine was designed and synthesized. Its light-emission property was studied in detail, and a strong energy transfer from peripheral chromophores to the phthalocyanine core was observed. The compound exhibited strong two-photon absorption responses with a two-photon absorption cross-section up to 1153 GM when irradiated with a picosecond laser in the wavelength range of 800-870 nm, and gave good singlet oxygen generation.

引用

页码：1804 / 1809

页数：6

共 14 条

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