Bifunctional N-heterocyclic carbene ligands for Cu-catalyzed direct C-H carboxylation with CO2

被引：33

作者：

Park, Da-Ae ^{[1
]}

Ryu, Ji Yeon ^{[2
]}

Lee, Junseong ^{[2
]}

Hong, Sukwon ^{[1
,3
]}

机构：

[1] Gwangju Inst Sci & Technol, Dept Chem, 123 Cheomdan Gwagi Ro, Gwangju 61005, South Korea

[2] Chonnam Natl Univ, Dept Chem, 77 Yongbong Ro, Gwangju 61186, South Korea

[3] Gwangju Inst Sci & Technol, Sch Mat Sci & Engn, 123 Cheomdan Gwagiro, Gwangju 61005, South Korea

来源：

RSC ADVANCES | 2017年 / 7卷 / 83期

关键词：

CROSS-COUPLING REACTIONS; CARBON-DIOXIDE; POLAR MONOMERS; COPPER(I) COMPLEXES; DIRECT AMINATION; NHC COMPLEXES; BONDS; COPOLYMERIZATION; ETHYLENE; TRANSFORMATION;

D O I：

10.1039/c7ra11414a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Diethylene glycol-functionalized imidazo[1,5-a] pyridin-3-ylidenes (DEG-ImPy) have been developed as bifunctional N-heterocyclic carbene ligands. The DEG-ImPy Cu(I) complexes efficiently catalyzed the direct C-H carboxylation of benzoxazole with CO2, showing higher isolated yields than those with the N,N'-(2,6-diisopropylphenyl) imidazolylidene Cu catalyst.

引用

页码：52496 / 52502

页数：7

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