Template-Assisted Formation of Fullerenes from Short-Chain Hydrocarbons by Supported Platinum Nanoparticles

被引：10
|
作者：
Vines, Francesc [1 ]
Goerling, Andreas [1 ]
机构：
[1] Univ Erlangen Nurnberg, Lehrstuhl Theoret Chem & Interdisciplinary Ctr In, D-91058 Erlangen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 20期
关键词：
dehydrogenation; density functional calculations; fullerenes; nanostructured templates; platinum nanoparticles; METHANE ACTIVATION; CHEMICAL-SYNTHESIS; METAL-SURFACES; ADSORPTION; DEHYDROGENATION; CATALYSTS; PT(111); C-60; CYCLODEHYDROGENATION; DECOMPOSITION;
D O I：
10.1002/anie.201006588
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A C60 bubble-maker: Induced by platinum nanoparticle templates, carbon atoms formed during the dehydrogenation of small hydrocarbon molecules gather and, reaching a certain coverage on the nanoparticle templates, form fullerenes (see picture). The tailor-made Pt nanoparticle templates exhibit defined shapes and sizes and are supported on inert or basic oxide supports. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4611 / 4614
页数：4
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