A cage-monoterpene indole alkaloid from Alstonia scholaris

被引:136
作者
Cai, Xiang-Hai [1 ]
Tan, Qin-Gang [1 ]
Liu, Ya-Ping [1 ]
Feng, Tao [1 ]
Du, Zhi-Zhi [1 ]
Li, We-Qi [1 ]
Luo, Xiao-Dong [1 ]
机构
[1] Chinese Acad Sci, Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650204, Peoples R China
关键词
D O I
10.1021/ol702682h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An unprecedented cage-like alkaloid, scholarisine A was isolated from the leaves of Alstonia scholaris and its structure determined on the basis of 1 D and 2D NMR, FTIR, UV, and high-resolution mass spectroscopic data. This alkaloid might be derived from picrinine via oxygenation, rearrangement, and lactonization.
引用
收藏
页码:577 / 580
页数:4
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