Convenient synthesis of tropos phosphine-oxazoline ligands

被引:14
作者
Liu YuanYuan [1 ]
Yang GuoQiang [1 ]
Yao DongMei [1 ]
Tian FengTao [1 ]
Zhang WanBin [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China
基金
中国国家自然科学基金;
关键词
tropos phosphine-oxazoline ligands; chirality-inducement; electronic property; steric property; BISOXAZOLINE LIGANDS; ASYMMETRIC HYDROGENATION; HIGH ENANTIOSELECTIVITY; BIPHENYL BACKBONE; PD; COMPLEXES; 5,5'-POSITION; CATALYSIS; BRIDGE; PALLADIUM(0);
D O I
10.1007/s11426-010-4172-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tropos phosphine-oxazoline ligands have shown interesting coordination behavior and excellent chiral inducing ability in asymmetry catalysis. Here we present a convenient and economic route for the synthesis of this type of ligands. According to this new route, the ligands with different electronic and steric properties have been prepared successfully.
引用
收藏
页码:87 / 94
页数:8
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