Carbonatation and Decarbonatation Kinetics in the La2O3-La2O2CO3 System under CO2 Gas Flows

被引：62

作者：

Bakiz, Bahcine ^{[1
,2
]}

Guinneton, Frederic ^{[1
]}

Arab, Madjid ^{[1
]}

Benlhachemi, Abdeljalil ^{[2
]}

Villain, Sylvie ^{[1
]}

Satre, Pierre ^{[1
]}

Gavarri, Jean-Raymond ^{[1
]}

机构：

[1] Univ SUD Toulon & Var, CNRS, Inst Mat Microelect & Nanosci Provence, UMR 6242, F-83957 La Garde, France

[2] Univ Ibn Zohr, Fac Sci, Lab Mat & Environm, Agadir 80000, Morocco

来源：

ADVANCES IN MATERIALS SCIENCE AND ENGINEERING | 2010年 / 2010卷

关键词：

NO REDUCTION; DECOMPOSITION; CH4; OXYCARBONATE; DESORPTION; ABSORPTION; CATALYST; LA2O3; H2O;

D O I：

10.1155/2010/360597

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The carbonatation of La2O3 oxide and the decarbonatation of lanthanum carbonate phase La2O2CO3 are investigated using thermal and thermogravimetry analyses under CO2 gas flow. The initial phase La2O3 is first elaborated from pyrolysis of a LaOHCO3 precursor. Then, thermal and thermogravimetry analyses are carried out under CO2 flow, as temperature increases then decreases. The carbonatation kinetics of La2O3 is determined at three fixed temperatures. Electrical impedance spectroscopy is performed to determine the electrical responses associated with ionic mobilities and phase changes, in the temperature range 25 to 900 degrees C. The electrical conduction during heating under CO2 gas flow should be linked to two regimes of ionic conduction of the carbonate ions. From these electrical measurements, the ionic mobility of carbonate ions CO32- is found to be close to 0.003.10(-4) cm(2) s(-1) V-1 at 750 degrees C for the monoclinic La2O2CO3 phase.

引用

页数：6

共 23 条

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